Preparation of BaTiO3 Thick Film by an Interfacial Polymerization Method

Mitsunobu Iwasaki; Won-Kyu Park

Korean Journal of Materials Research, Vol.17, No.10, 548-554, October, 2007

DOI10.3740/MRSK.2007.17.10.548 Export Citation

Preparation of BaTiO3 Thick Film by an Interfacial Polymerization Method

Mitsunobu Iwasaki, and Won-Kyu Park^{1, †}

Department of Applied Chemistry, School of Science & Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka, 577-8502, Japan, Korea
¹Department of Material Engineering, Graduate School of Paichai University, 439-6, Doma-2 dong, Seo-gu, Daejeon, Korea

E-mail:

[ BaTiO3 ] thick film by an interfacial polymerization method was prepared at the liquid/liquid interface between benzyl alcohol saturated solution with the basic catalyst [diethyl amine (NHEt2) or triethylamine (NEt3)], and the water dissolved with TiO2 and Ba (CH3 COO)2. The film thickness increased gradually with an increase in diethyl amine(NHEt2) or triethylamine(NEt3) volume and the reaction time. The homogeneity of BaTiO3 thick film after sintered at 600oC was confirmed by EPMA analysis, which showed that both of Ba and Ti element were homogeneously distributed on the surface as well as in the perpendicular direction of the film. The thickness of BaTiO3 film obtained by this process was 8/75um.

Keywords:BaTiO3 thick film;Polymerization method;Liquid/liquid interface;Basic catalyst

[References]

Kingon AI, Streiffer SK, Current Opinion in Solid State & Materials Science, 4(1), 39 (1999)
Schwarzkopf J, Fornari R, in Crystal Growth and Characterization of Materials, 52(3), 159 (2006)
Asamaki T, Introduction to the fabrication of thin films, Nikkan kogyoshinnbunn-sha (1984) (in Japanese) (1984)
Chiba T, Itoh K, Matsumoto O, Thin Solid Films, 300(1), 6 (1997)
Jianming Z, Hong W, Ming W, Suxia S, Zuo W, Chenglu L, Journal of Physics D, 31(19), 2416 (1998)
Fundamental knowledge of advanced materials, Ed. by Society of Materials Science, Japan (1991) (in Japanese) (1991)
Yamane M, Iwasaki M, Ito S, Ceramic Transactions, 81, 113 (1998)
Saka S, The science of sol-gel process, Chapter 9, Published by Agne Shouhusya (1998) (in Japanese) (1998)
Munuera G, Gonzalez-Elipe AR, Fernandez A, Malet P, Espinos JP, J. Chern. Soc. Faraday Trans.1, 85(6), 1279 (1989)
Bass Jr CF, Mesmer RE, The hydrolysis of cations, Krieger Publishing Company, 147 (1976)
Experiments in inorganic qualitative analysis, Ed. by Kyoto University, Kyoritushuppan, (1994) (in Japanese) (1994)

[1] Kingon AI, Streiffer SK, Current Opinion in Solid State & Materials Science, 4(1), 39 (1999)

[2] Schwarzkopf J, Fornari R, in Crystal Growth and Characterization of Materials, 52(3), 159 (2006)

[3] Asamaki T, Introduction to the fabrication of thin films, Nikkan kogyoshinnbunn-sha (1984) (in Japanese) (1984)

[4] Chiba T, Itoh K, Matsumoto O, Thin Solid Films, 300(1), 6 (1997)

[5] Jianming Z, Hong W, Ming W, Suxia S, Zuo W, Chenglu L, Journal of Physics D, 31(19), 2416 (1998)

[6] Fundamental knowledge of advanced materials, Ed. by Society of Materials Science, Japan (1991) (in Japanese) (1991)

[7] Yamane M, Iwasaki M, Ito S, Ceramic Transactions, 81, 113 (1998)

[8] Saka S, The science of sol-gel process, Chapter 9, Published by Agne Shouhusya (1998) (in Japanese) (1998)

[9] Munuera G, Gonzalez-Elipe AR, Fernandez A, Malet P, Espinos JP, J. Chern. Soc. Faraday Trans.1, 85(6), 1279 (1989)

[10] Bass Jr CF, Mesmer RE, The hydrolysis of cations, Krieger Publishing Company, 147 (1976)

[11] Experiments in inorganic qualitative analysis, Ed. by Kyoto University, Kyoritushuppan, (1994) (in Japanese) (1994)