B2형 금속간화합물 NiTi 중에 L21형 Ni2AlTi상의 석출

한창석; Chang-Suk Han

Korean Journal of Materials Research, Vol.17, No.8, 420-424, August, 2007

DOI10.3740/MRSK.2007.17.8.420 Export Citation

B2형 금속간화합물 NiTi 중에 L21형 Ni2AlTi상의 석출

Precipitation of L21-type Ni2AlTi Phase in B2-type Intermetallic Compounds NiTi

한창석^†

호서대학교 국방과학기술학과

Chang-Suk Han^†

Dept. of Defense Science & Technology, Hoseo University, 165 Sechul-Ri, Baebang-Myun, Asan City, Chungnam 336-795, Korea

E-mail:

Precipitation behavior has been studied in NiTi-based ordered alloy using transmission electron microscopy. The hardness after solution treatment is high in NiTi alloy suggesting the large contribution of solid solution strengthening in this alloy system. However, the amount of age hardening is not large as compared to the large microstructural variations during aging. At the beginning of aging, the precipitates keep a lattice coherency with the NiTi matrix. By longer periods of aging precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. Misfit dislocations, which are observed on {100} planes of H-precipitates have the Burgers vector of a <100> with a pure edge type. The lattice misfits of system is estimated from the spacings of misfit dislocations to be 1.3% at 1273 K. The lattice misfits decrease with increasing aging temperature in this system.

Keywords:intermetallic compound;precipitation;age hardening

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[1] Yamaguchi M, Umakoshi Y, Yamane T, Phil. Mag. A, 50, 205 (1984)

[2] Nathal MV, Ordered Intermetallics-Physical Metallurgy and Mechanical Behaviour, 213, 541 (1992)

[3] Polvani RS, Tzeng WS, Strutt PR, Metall. Trans. A, 7A, 33 (1976)

[4] Bendersky LA, Voorhees PW, Boettinger WJ, Johnson WC, Scripta Metall., 22, 1029 (1988)

[5] Veyssiere P, Ordered Intermetallics-Physical Metallurgy and Mechanical Behaviour, 213, 165 (1992)

[6] Miyazaki TM, Mat. Sci. Eng. A, 110, 175 (1989)

[7] Johnson WC, Voorhees PW, J. Appl. Phys., 61, 1610 (1987)

[8] Murata Y, Koyama T, Morinaga M, Hashi- zume R, Doi M, Materials for advanced power engineering, 1201 (2002)

[9] Villars P, Calvert LP, Peason's Handbook of Crystallographic Data for Intermetallic Phases, (1985) (1985)

[10] Enomoto M, Kumeta T, Scripta mat., 44, 481 (2001)

[11] Kaufman L, Nesor H, Metal. Trans., 5, 1623 (1974)