졸-겔법을 이용한 실리카 핵을 가지는 하이브리드 안료의 제조와 잉크젯 분산 잉크로서 응용

전영민; 김종규; 공명선; Young-Min Jeon; Jong-Gyu Kim; Myoung-Seon Gong

Korean Journal of Materials Research, Vol.16, No.10, 599-605, October, 2006

DOI10.3740/MRSK.2006.16.10.599 Export Citation

졸-겔법을 이용한 실리카 핵을 가지는 하이브리드 안료의 제조와 잉크젯 분산 잉크로서 응용

Preparation of Silica Core-Hybrid Pigment via Sol-Gel Process and It's Application for Inkjet Dispersion Ink

전영민, 김종규, 공명선 ^†

단국대학교 화학과

Young-Min Jeon, Jong-Gyu Kim, and Myoung-Seon Gong^†

Department of Chemistry and Institute of Basic Science, Dankook University, Chungnam 330-714, Korea

E-mail:

-(3-triethoxysilylpropyl)-1,4-diaminoanthrquinone-2,3-dicarboximide (TESP-DADI), an organic blue pigment, has been prepared and incorporated into silica solid matrix reacting triethyl orthosilicate (TEOS) via sol-gel method. Morphology and microstructure of resulting hybrid pigment were studied employing SEM and TEM. The micrographs and particle size distributions showed that uniform pigment can be obtained employing TEOS-based sol-gel method forming silica core. Particle size distribution of dispersed pigment in water was examined using the technique of dynamic light scattering. The ensuing pigment dispersion ink was subjected to various physicochemical evaluation such as viscosity, surface tension, inkjet stability, storage stability, and color change as inkjet ink using spectrophotometric, and microscopic techniques.

Keywords:Blue Anthraquinone dye;sol-gel process;hybrid pigment;inkjet dispersion ink

[References]

Avnir D, Levy D, Reisfeld R, J. Chem. Phys., 88, 5969 (1984)
Avnir D, Kaufmann VR, J. Non-Crys. Solids, 74, 395 (1985)
Whitehurst C, Shaw DJ, King TA, SPIE Proc., 1382, 183 (1990)
Brinker J, Scherer G, Sol-Gel Science, Academic press, New York, 1989 (1989)
Brinker CJ, J. Non-Crys. Solids, 100, 31 (1988)
Lev O, Tsionsky M, Rabinovich L, Glezer V, Sampath S, Pankratov I, Gun J, Anal. Chem., 67, 22A (1995)
Avnir D, Acc. Chem. Res., 28, 328 (1995)
Ledger R, Stellwagen EJ, Chromatogr., 299, 175 (1984)
Giesche H, Matijevic' E, Dyes and Pigments, 17, 323 (1991)
Wu GW, Koliadima A, Her YS, Matijevic E, J. Colloid Interface Sci., 195(1), 222 (1997)
Winnik FM, Keoshkerian B, Fuller JR, Hofstra PG, Dyes and Pigments, 14, 101 (1990)
Jesionowski T, Dyes and Pigments, 55, 133 (2002)
Jesionowski T, Pokora M, Tylus W, Dec A, Krysztafkiewicz A, Dyes and Pigments, 57, 29 (2003)
Jesionowski T, Krysztafkiewicz A, Binkovski S, Dyes and Pigments, 65, 267 (2005)
US Patent 4,566,908 (1986) (1986)
US Patent 4,576,888 (1986) (1986)
US Patent 4,877,451 (1989) (1989)
Winnik FM, Kcoshkerian B, Fuller JR, Hofstra PG, Dyes and Pigments, 14, 101 (1990)
Matijevic' E, J. Eur. Ceram. Soc., 18, 1357 (1998)
Hsu WP, Yu R, Matijevic' E, Dyes and Pigments, 19, 222 (1992)
Tentorino A, Matijevic' E, Kratobvil JP, J. Colloid. & Interf. Sci., 77, 418 (1980)
Matijevic' E, Aiken B, Hsu WP, J. Am. Ceram. Soc., 71, 845 (1988)
Balbyshev VN, Anderson KL, Sinsawat A, Fanner BL, Donley MS, Prog. Org. Coatings, 47, 337 (2003)

[Related Articles]

[1] Avnir D, Levy D, Reisfeld R, J. Chem. Phys., 88, 5969 (1984)

[2] Avnir D, Kaufmann VR, J. Non-Crys. Solids, 74, 395 (1985)

[3] Whitehurst C, Shaw DJ, King TA, SPIE Proc., 1382, 183 (1990)

[4] Brinker J, Scherer G, Sol-Gel Science, Academic press, New York, 1989 (1989)

[5] Brinker CJ, J. Non-Crys. Solids, 100, 31 (1988)

[6] Lev O, Tsionsky M, Rabinovich L, Glezer V, Sampath S, Pankratov I, Gun J, Anal. Chem., 67, 22A (1995)

[7] Avnir D, Acc. Chem. Res., 28, 328 (1995)

[8] Ledger R, Stellwagen EJ, Chromatogr., 299, 175 (1984)

[9] Giesche H, Matijevic' E, Dyes and Pigments, 17, 323 (1991)

[10] Wu GW, Koliadima A, Her YS, Matijevic E, J. Colloid Interface Sci., 195(1), 222 (1997)

[11] Winnik FM, Keoshkerian B, Fuller JR, Hofstra PG, Dyes and Pigments, 14, 101 (1990)

[12] Jesionowski T, Dyes and Pigments, 55, 133 (2002)

[13] Jesionowski T, Pokora M, Tylus W, Dec A, Krysztafkiewicz A, Dyes and Pigments, 57, 29 (2003)

[14] Jesionowski T, Krysztafkiewicz A, Binkovski S, Dyes and Pigments, 65, 267 (2005)

[15] US Patent 4,566,908 (1986) (1986)

[16] US Patent 4,576,888 (1986) (1986)

[17] US Patent 4,877,451 (1989) (1989)

[18] Winnik FM, Kcoshkerian B, Fuller JR, Hofstra PG, Dyes and Pigments, 14, 101 (1990)

[19] Matijevic' E, J. Eur. Ceram. Soc., 18, 1357 (1998)

[20] Hsu WP, Yu R, Matijevic' E, Dyes and Pigments, 19, 222 (1992)

[21] Tentorino A, Matijevic' E, Kratobvil JP, J. Colloid. & Interf. Sci., 77, 418 (1980)

[22] Matijevic' E, Aiken B, Hsu WP, J. Am. Ceram. Soc., 71, 845 (1988)

[23] Balbyshev VN, Anderson KL, Sinsawat A, Fanner BL, Donley MS, Prog. Org. Coatings, 47, 337 (2003)