Te-doped was prepared by the encapsulated induction melting, and its doping effects on the thermoelectric properties were investigated. Single phase was successfully obtained by the subsequent annealing at 773 K for 24 hrs. Tellurium atoms acted as electron donors by substituting antimony atoms. Thermoelectric properties were remarkably improved by the appropriate doping. Dimensionless figure of merit was obtained to be 0.83 at 700K for the specimen.