화학공학소재연구정보센터
Journal of Electroanalytical Chemistry, Vol.364, No.1-2, 135-141, 1994
Contribution to the Study of Differential-Pulse Polarography in the Case of Quasi-Reversible and Irreversible Simple Reactions
An exhaustive theoretical analysis of differential pulse polarography, irrespective of the rate of charge transfer, based on the model of plane non-convective diffusion, is presented. The theoretical treatment is valid in the case of redox systems without chemical complication or reactant adsorption. This study allows the characterization and quantitative description of quasi-reversible waves. It also shows how the sensitivity of the method can be improved for irreversible reactions.