화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 212-220, January, 2015
DOI10.1016/j.jiec.2014.02.027  Export Citation
Effect of diluent polarity on membrane stability in the separation of trace Pd(II) from wastewater by HFSLM using LIX84-I
Kraiwith Wongkaew, Ura Pancharoen, Suphot Phatanasri†, Natchanun Leepipatpiboon1, †, and Anchaleeporn W. Lothongkum2
  • Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand
  • 1Chromatography and Separation Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand
  • 2Department of Chemical Engineering, Faculty of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, Thailand
E-mail:,
In a liquid membrane, the type of diluents for the selected extractant plays an important role in membrane stability and separation efficiency. High Pd(II) extraction and stripping of 96% and 91%, respectively, were observed by HFSLM under a feed pH 2, 5% (v/v) LIX84-I dissolved in kerosene and a mixture of 0.8 M NH2CSNH2 with 1 M HCl as a stripping solution. The highest stability was attained at 350 min by using hexane as a diluent. Finally, the calculated activation energy (Ea) of 30 kJ/mol implied that the separation of Pd(II) was controlled by the diffusion and chemical reaction.
Keywords:Palladium;Diluent;Polarity;HFSLM;Membrane stability
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