화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 369-377, January, 2015
DOI10.1016/j.jiec.2014.02.047  Export Citation
Adsorption/desorption of cationic dye on surfactant modified mesoporous carbon coated monolith: Equilibrium, kinetic and thermodynamic studies
Mohamad Rasool Malekbala1, Moonis Ali Khan2, Soraya Hosseini1, Luqman Chuah Abdullah1, 3, and Thomas S.Y. Choong1, 3, †
  • 1Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
  • 2Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
  • 3INTROP, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
E-mail:
Surfactant modified carbon coated monolith was used as an adsorbent for methylene blue (MB) adsorption. Effects of pH, salt, contact time, initial dye concentrations and temperature on dye adsorption were studied. Higher solution pH favoured MB adsorption. Furthermore, kinetics study showed that the adsorption could be better represented by the pseudo-second-order model. Linear and non-linear isotherm studies revealed better fitting of Langmuir model to adsorption data with maximum monolayer adsorption capacity 388 mg/g. The adsorption was found to be spontaneous and endothermic. Desorption studies indicate that 0.1 N HCl exhibits higher elution efficiency (82.1%) with appreciable quantitative MB recovery.
Keywords:Mesoporous carbon coated monolith;Surfactant (F-127);Methylene blue;Desorption;Regeneration
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