Heterogeneous photodegradation of 2,4-dichlorophenol using FeO doped onto nano-particles of zeolite P

Alireza Nezamzadeh-Ejhieh; Zahra Ghanbari-Mobarakeh

Journal of Industrial and Engineering Chemistry, Vol.21, 668-676, January, 2015

DOI10.1016/j.jiec.2014.03.035 Export Citation

Heterogeneous photodegradation of 2,4-dichlorophenol using FeO doped onto nano-particles of zeolite P

Alireza Nezamzadeh-Ejhieh^†, and Zahra Ghanbari-Mobarakeh

Department of Chemistry, Shahreza Branch, Islamic Azad University, PO Box 311-86145, Shahreza, Isfahan, Iran

E-mail:

Photocatalytic degradation of 2,4-dichlorophenol was studied using FeO-doped onto nano-particles of zeolite P (FeO-NP). FeO/NP was prepared by ion exchange and calcination procedures. The samples were characterized by FT-IR, SEM and DRS. UV-vis, HPLC and COD were employed to calculate the degradation extent of the pollutant. The results confirmed that the degradation efficiency of the method strongly dependent to experimental parameters such as: pH, catalyst concentration, substrate concentration, active component value (FeO) loading, presence of H2O2 and inorganic Cl- and SO4 2- anions. The firstorder kinetics model was used to study the kinetics of the method.

Keywords:Photocatalytic degradation;Nano-particles;Zeolite P;2,4-dichlorophenol;Heterogeneous catalysis

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[Referenced By]

[1] Lathasree S, Rao AN, SivaSankar B, Sadasivam V, Rengaraj K, J. Mol. Catal. A-Chem., 223(1-2), 101 (2004)

[2] Shukla PR, Wang S, Ang HM, Tade MO, Sep. Purif. Technol., 70, 344 (2010)

[3] Kilic M, Cinar Z, J. Mol. Struct. THEOCHEM, 851, 263 (2008)

[4] Ranjit PJD, Palanivelu K, Lee CS, Korean J. Chem. Eng., 25(1), 112 (2008)

[5] Jia J, Zhang S, Wang P, Wang H, J. Hazard. Mater., 29, 205 (2012)

[6] Pardeshi SK, Patil AB, Sol. Energy, 82(8), 700 (2008)

[7] Balasubramanian A, Venkatesan S, Desalination, 289, 27 (2012)

[8] Priya MH, Madras G, Ind. Eng. Chem. Res., 45(2), 482 (2006)

[9] Nam W, Woo K, Han G, J. Ind. Eng. Chem., 15(3), 348 (2009)

[10] Shanti M, Kuzhalosai V, Indian J. Chem., 51, 428 (2012)

[11] Bhati I, Kumar A, Ameta SC, J. Iran. Chem. Res., 3, 211 (2010)

[12] Nezamzadeh-Ejhieh A, Shirvani K, J. Chem., Article ID 541736, 11 (2013)

[13] Sun W, Li J, Yao G, Jiang M, Zhang F, Catal. Commun., 16, 90 (2011)

[14] Nezamzadeh-Ejhieh A, Salimi Z, Desalination, 280(1-3), 281 (2011)

[15] Azizi SN, Samadi-Meybodi AR, Yarmohammadi M, Open J. Inorg. Chem., 2(1), 1 (2012)

[16] Nezamzadeh-Ejhieh A, Hushmandrad S, Appl. Catal. A: Gen., 388(1-2), 149 (2010)

[17] Nezamzadeh-Ejhieh A, Khorsandi M, Iran. J. Catal., 1(2), 99 (2011)

[18] Dukkanci M, Gunduz G, Yilmaz S, Prihod'ko RV, J. Hazard. Mater., 181(1-3), 343 (2010)

[19] Kasiri MB, Aleboyeh H, Aleboyeh A, Appl. Catal. B: Environ., 84(1-2), 9 (2008)

[20] Navalon S, Alvaro M, Garcia H, Appl. Catal. B: Environ., 99(1-2), 1 (2010)

[21] Emara MM, Tourky ASM, El-Moselhy MM, J. Hazard. Mater., 166(1), 514 (2009)

[22] Abdul JM, Kumar M, Vigneswaran S, Kandasamy J, J. Ind. Eng. Chem., 18(1), 137 (2012)

[23] Jung HJ, Hong JS, Suh JK, J. Ind. Eng. Chem., 19(4), 1325 (2013)

[24] Zhan BZ, White MA, Lumsden M, Mueller-Neuhaus J, Robertson KN, Cameron TS, Gharghouri M, Chem. Mater., 14, 3636 (2002)

[25] Brazlauskas M, Kitrys S, Chin. J. Catal., 29(1), 25 (2008)

[26] Faghihian H, Kamali M, Int. J. Environ. Pollut., 19(6), 557 (2003)

[27] Pal P, Das JK, Bandyopadhyay S, Ultrason. Sonochem., 20, 314 (2012)

[28] Covarrubias C, Gracia F, Palza H, Appl. Catal. A: Gen., 384(1-2), 186 (2010)

[29] Kondru AK, Kumar P, Chand S, J. Hazard. Mater., 166(1), 342 (2009)

[30] Yee M, Yaacob II, Mater. Res. Soc., 19, 930 (2004)