Oxidative dehydrogenation of butenes to butadiene over Bi-Fe-Me(Me = Ni, Co, Zn, Mn and Cu)-Mo oxide catalysts

Jung-Hyun Park; Chae-Ho Shin

Journal of Industrial and Engineering Chemistry, Vol.21, 683-688, January, 2015

DOI10.1016/j.jiec.2014.03.037 Export Citation

Oxidative dehydrogenation of butenes to butadiene over Bi-Fe-Me(Me = Ni, Co, Zn, Mn and Cu)-Mo oxide catalysts

Jung-Hyun Park, and Chae-Ho Shin^†

School of Environmental, Urban and Chemical Engineering, Chungbuk National University, Chungbuk, Cheongju 361-763, Republic of Korea

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BiFe0.65Me0.05Mo oxide catalysts promoted with different metals (Me = Ni, Co, Zn, Mn and Cu) were prepared and the effects of the transition metal addition based on multicomponent BiFeMo oxide catalysts have been investigated for the oxidative dehydrogenation of butenes to 1,3-butadiene. It has been found that the catalytic activity of BiFe0.65Me0.05Mo oxide catalysts depends on the nature of the metals employed, varying in the order of Ni > Co > Zn > Mn > Cu. Temperature-programed re-oxidation measurements revealed that the catalytic activity of the BiFe0.65Me0.05Mo oxide catalysts was well correlated with the oxygen mobility of the catalysts.

Keywords:Oxidative dehydrogenation;Multicomponent BiFeMo oxide catalysts;Temperature-programed re-oxidation;Transition metals;1,3-Butadiene

[References]

Ertl G, Knozinger H, Weitkamp J, Handbook of Heterogeneous Catalysis, VCH, Weinheim (1997)
White WC, Chem. Biol. Interact., 166, 10 (2007)
Batist A, Moesdijk CGM, Matsuura I, Schuit GCA, J. Catal., 20, 40 (1971)
Wolfs MWJ, Batist A, J. Catal., 32, 25 (1974)
Park JH, Noh HR, Park JW, Roh KH, Jung KD, Shin CH, Res. Chem. Intermed., 37, 1125 (2011)
Kung HH, Kung MC, Adv. Catal., 33, 159 (1985)
Lee H, Jung JC, Kim H, Chung YM, Kim TJ, Lee SJ, Oh SH, Kim YS, Song IK, Korean J. Chem. Eng., 26(4), 994 (2009)
Nieto JML, Concepcion P, Dejoz A, Melo F, Knozinger H, Vazquez MI, Catal. Today, 61(1-4), 361 (2000)
Millet JMM, Ponceblanc H, Coudurier G, Herrmann JM, J. Catal., 142, 381 (1993)
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Notermann T, Keulks GW, Skliarov A, Maximov Y, Margolis LY, Krylov OV, J. Catal., 39, 286 (1975)
Park JH, Noh H, Park JW, Row K, Jung KD, Shin CH, Appl. Catal. A: Gen., 431, 137 (2012)
Park JH, Row KH, Shin CH, Catal. Commun., 31, 76 (2013)
Brazdil JF, Suresh DD, Grasselli RK, J. Catal., 66, 347 (1980)
Prasada Rao TSR, Krishnamurthy KR, J. Catal., 95, 209 (1985)
Golunski SE, Walker AP, J. Catal., 204(1), 209 (2001)
Miura H, Morikawa Y, Shirasaki T, J. Catal., 39, 22 (1975)
Voge HH, Adams CR, Adv. Catal., 17, 151 (1967)
Jung JC, Lee HW, Kim HS, Chung YM, Kim TJ, Lee SJ, Oh SH, Kim YS, Song IK, Catal. Commun., 9, 1676 (2008)
Jung JC, Lee HW, Song IK, Catal. Surv. Asia, 13, 78 (2009)
Barannik GG, Veniaminov SA, React. Kinet. Catal. Lett., 16, 163 (1981)
Kung MC, Cheng WH, Kung HH, J. Phys. Chem., 83, 1737 (1979)

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[1] Ertl G, Knozinger H, Weitkamp J, Handbook of Heterogeneous Catalysis, VCH, Weinheim (1997)

[2] White WC, Chem. Biol. Interact., 166, 10 (2007)

[3] Batist A, Moesdijk CGM, Matsuura I, Schuit GCA, J. Catal., 20, 40 (1971)

[4] Wolfs MWJ, Batist A, J. Catal., 32, 25 (1974)

[5] Park JH, Noh HR, Park JW, Roh KH, Jung KD, Shin CH, Res. Chem. Intermed., 37, 1125 (2011)

[6] Kung HH, Kung MC, Adv. Catal., 33, 159 (1985)

[7] Lee H, Jung JC, Kim H, Chung YM, Kim TJ, Lee SJ, Oh SH, Kim YS, Song IK, Korean J. Chem. Eng., 26(4), 994 (2009)

[8] Nieto JML, Concepcion P, Dejoz A, Melo F, Knozinger H, Vazquez MI, Catal. Today, 61(1-4), 361 (2000)

[9] Millet JMM, Ponceblanc H, Coudurier G, Herrmann JM, J. Catal., 142, 381 (1993)

[10] Vasil'ev AN, Galich PN, Chem. Tech. Fuels Oils, 33(3), 185 (1997)

[11] Notermann T, Keulks GW, Skliarov A, Maximov Y, Margolis LY, Krylov OV, J. Catal., 39, 286 (1975)

[12] Park JH, Noh H, Park JW, Row K, Jung KD, Shin CH, Appl. Catal. A: Gen., 431, 137 (2012)

[13] Park JH, Row KH, Shin CH, Catal. Commun., 31, 76 (2013)

[14] Brazdil JF, Suresh DD, Grasselli RK, J. Catal., 66, 347 (1980)

[15] Prasada Rao TSR, Krishnamurthy KR, J. Catal., 95, 209 (1985)

[16] Golunski SE, Walker AP, J. Catal., 204(1), 209 (2001)

[17] Miura H, Morikawa Y, Shirasaki T, J. Catal., 39, 22 (1975)

[18] Voge HH, Adams CR, Adv. Catal., 17, 151 (1967)

[19] Jung JC, Lee HW, Kim HS, Chung YM, Kim TJ, Lee SJ, Oh SH, Kim YS, Song IK, Catal. Commun., 9, 1676 (2008)

[20] Jung JC, Lee HW, Song IK, Catal. Surv. Asia, 13, 78 (2009)

[21] Barannik GG, Veniaminov SA, React. Kinet. Catal. Lett., 16, 163 (1981)

[22] Kung MC, Cheng WH, Kung HH, J. Phys. Chem., 83, 1737 (1979)