Synthesis of Au/Pd bimetallic nanoparticles and their application in the Suzuki coupling reaction

Mahmoud Nasrollahzadeh; Abbas Azarian; Mehdi Maham; Ali Ehsani

Journal of Industrial and Engineering Chemistry, Vol.21, 746-748, January, 2015

DOI10.1016/j.jiec.2014.04.006 Export Citation

Synthesis of Au/Pd bimetallic nanoparticles and their application in the Suzuki coupling reaction

Mahmoud Nasrollahzadeh^†, Abbas Azarian¹, Mehdi Maham², and Ali Ehsani

Department of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, Iran
¹Department of Physics, University of Qom, Qom, Iran
²Department of Chemistry, Aliabad Katoul Branch, Islamic Azad University, Aliabad Katoul, Iran

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This communication reports on the synthesis and use of Au/Pd bimetallic nanoparticles, as separable catalysts for ligand-free Suzuki coupling reactions. This method has the advantages of high yields, elimination of homogeneous catalysts, green reaction conditions, simple methodology and easy work up. Catalytic efficiency remains unaltered even after several repeated cycles. The catalyst was characterized using the SEM and EDS.

Keywords:Nanoparticles;Suzuki;Gold;Palladium;Ligand-free

[References]

Fihri A, Bouhrara M, Nekoueishahraki B, Basset JM, Chem. Soc. Rev., 40, 5181 (2011)
Favier I, Madec D, Teuma E, Gomez M, Curr. Org. Chem., 15, 3127 (2011)
Gladysz JA, Pure Appl. Chem., 273, 1319 (2001)
Michalik J, Narayana M, Kevan L, J. Phys. Chem., 89, 4553 (1985)
Roucoux A, Schulz J, Patin H, Chem. Rev., 102(10), 3757 (2002)
Huang Y, Zheng Z, Liu T, Lu J, Lin Z, Li H, Cao R, Catal. Commun., 14, 27 (2011)
Narayanan R, El-Sayed MA, J. Am. Chem. Soc., 125(27), 8340 (2003)
Daniel MC, Astruc D, Chem. Soc. Rev., 104, 293 (2004)
Nasrollahzadeh M, Rostami-Vartooni A, Ehsani A, Moghadam M, J. Mol. Catal. A-Chem., 387, 123 (2014)
Ehsani A, Jaleh B, Nasrollahzadeh M, J. Power Sources, 257, 300 (2014)
Nasrollahzadeh M, Ehsani A, Rostami-Vartouni A, Ultrason. Sonochem., 21, 275 (2014)
Ehsani A, Babaei F, Nasrollahzadeh M, Appl. Surf. Sci., 283, 1060 (2013)
Fakhri P, Jaleh B, Nasrollahzadeh M, J. Mol. Catal. A-Chem., 383, 17 (2014)
Habibi D, Heydari S, Nasrollahzadeh M, J. Chem. Res., 36, 573 (2012)
Habibi D, Nasrollahzadeh M, Sahebekhtiari H, J. Mol. Catal. A-Chem., 378, 148 (2013)
Habibi D, Nasrollahzadeh M, Mehrabi L, Mostafaee S, Monatsh. Chem., 144, 725 (2012)
Nasrollahzadeh M, Ehsani A, Maham M, Synlett, 25, 505 (2014)
Mandali PK, Chand DK, Catal. Commun., 31, 16 (2013)
Heugebaert TSA, De Corte S, Sabbe T, Hennebel T, Verstraete W, Boon N, Stevens CV, Tetrahedron Lett., 53, 1410 (2012)
Peng YY, Liu J, Lei X, Yin Z, Green Chem., 12, 1072 (2010)

[Referenced By]

[1] Fihri A, Bouhrara M, Nekoueishahraki B, Basset JM, Chem. Soc. Rev., 40, 5181 (2011)

[2] Favier I, Madec D, Teuma E, Gomez M, Curr. Org. Chem., 15, 3127 (2011)

[3] Gladysz JA, Pure Appl. Chem., 273, 1319 (2001)

[4] Michalik J, Narayana M, Kevan L, J. Phys. Chem., 89, 4553 (1985)

[5] Roucoux A, Schulz J, Patin H, Chem. Rev., 102(10), 3757 (2002)

[6] Huang Y, Zheng Z, Liu T, Lu J, Lin Z, Li H, Cao R, Catal. Commun., 14, 27 (2011)

[7] Narayanan R, El-Sayed MA, J. Am. Chem. Soc., 125(27), 8340 (2003)

[8] Daniel MC, Astruc D, Chem. Soc. Rev., 104, 293 (2004)

[9] Nasrollahzadeh M, Rostami-Vartooni A, Ehsani A, Moghadam M, J. Mol. Catal. A-Chem., 387, 123 (2014)

[10] Ehsani A, Jaleh B, Nasrollahzadeh M, J. Power Sources, 257, 300 (2014)

[11] Nasrollahzadeh M, Ehsani A, Rostami-Vartouni A, Ultrason. Sonochem., 21, 275 (2014)

[12] Ehsani A, Babaei F, Nasrollahzadeh M, Appl. Surf. Sci., 283, 1060 (2013)

[13] Fakhri P, Jaleh B, Nasrollahzadeh M, J. Mol. Catal. A-Chem., 383, 17 (2014)

[14] Habibi D, Heydari S, Nasrollahzadeh M, J. Chem. Res., 36, 573 (2012)

[15] Habibi D, Nasrollahzadeh M, Sahebekhtiari H, J. Mol. Catal. A-Chem., 378, 148 (2013)

[16] Habibi D, Nasrollahzadeh M, Mehrabi L, Mostafaee S, Monatsh. Chem., 144, 725 (2012)

[17] Nasrollahzadeh M, Ehsani A, Maham M, Synlett, 25, 505 (2014)

[18] Mandali PK, Chand DK, Catal. Commun., 31, 16 (2013)

[19] Heugebaert TSA, De Corte S, Sabbe T, Hennebel T, Verstraete W, Boon N, Stevens CV, Tetrahedron Lett., 53, 1410 (2012)

[20] Peng YY, Liu J, Lei X, Yin Z, Green Chem., 12, 1072 (2010)