화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 971-979, January, 2015
DOI10.1016/j.jiec.2014.05.003  Export Citation
Application of response surface methodology to the decolorization by the electrochemical process using FePMo12O40 catalyst
Lin Yue, Li Wang, Feng Shi1, Jianbo Guo†, Jingliang Yang, Jing Lian, and Xiao Luo
  • Pollution Prevention Biotechnology Laboratory of Hebei Provience, School of Environmental Science and Engineering, Hebei University of Science and Technology, 050018, China
  • 1Hebei Research Academy of Environmental Sciences, 050000, China
E-mail:
In order to optimize the experimental conditions, the decolorization of Acid Red 3R by electrochemical oxidation process with catalyst FePMo12-APS-MS4A as packing was performed using response surface methodology (RSM). The microstructure and morphology of FePMo12-APS-MS4A were characterized with Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray fluorescence spectroscopy (XRF). Four control factors were throughly analyzed by means of RSM based on Box-Behnken design (BBD). Taking the decolorization efficiency as response value, a second order polynomial model was established. The model and analysis strongly indicated that the cell voltage and airflow caused positive, and the initial pH and inter-electrode distance caused negative effect on the decolorization efficiency. The interaction between cell voltage and initial pH, initial pH and airflow were also revealed. Under the optimal conditions, the color, COD and TOC removal efficiency reached 67.3%, 58.4% and 47.9% after 60 min. Liquid chromatography-mass spectrometry (LC-MS) analysis revealed that the dye molecule underwent a series of reduction and oxidation steps, including azo bond fracture, desulfonation and denitrogenation. The possible mechanisms involving in this reaction process were proposed.
Keywords:Response surface methodology;Electrochemical oxidation;Polyoxometalate;Azo dye
  1. Medina-Moreno SA, Perez-Cadena R, Jimenez-Gonzalez A, Tellez-Jurado A, Lucho-Constantino CA, Bioresour. Technol., 123, 452 (2012)
  2. Ozdemir S, Cirik K, Akman D, Sahinkaya E, Cinar O, Bioresour. Technol., 146, 135 (2013)
  3. Solanki K, Subramanian S, Basu S, Bioresour. Technol., 131, 564 (2013)
  4. Ferraz ERA, Oliveira GAR, Grando MD, Lizier TM, Zanoni MVB, Oliveira DP, J. Environ. Manage., 124, 108 (2013)
  5. Sun J, Li WJ, Li YM, Hu YY, Zhang YP, Bioresour. Technol., 142, 407 (2013)
  6. Gao HJ, Kan TT, Zhao SY, Qian YX, Cheng XY, Wu WL, Wang XD, Zheng LG, J. Hazard. Mater., 261, 83 (2013)
  7. Gao HJ, Zhao SY, Cheng XY, Wang XD, Zheng LQ, Chem. Eng. J., 223, 84 (2013)
  8. Mohan SV, Babu PS, Srikanth S, Sep. Purif. Methods, 118, 196 (2013)
  9. Georgiou D, Metallinou C, Aivasidis A, Voudrias E, Gimouhopoulos K, Biochem. Eng. J., 19, 75 (2004)
  10. Talarposhti AM, Donnelly T, Anderson GK, Water Res., 35, 425 (2001)
  11. Khehra MS, Saini HS, Sharma DK, Chadha BS, Chimni SS, Dyes Pigment., 70, 1 (2006)
  12. Gottlieb A, Shaw C, Smith A, Wheatley A, Forsythe S, J. Biotechnol., 101, 49 (2003)
  13. Anouzla A, Abrouki Y, Souabi S, Safi M, Rhbal H, J. Hazard. Mater., 166(2-3), 1302 (2009)
  14. Wang L, J. Environ. Manage., 102, 79 (2012)
  15. Devi LG, Kumar SG, Reddy KM, Munikrishnappa C, J. Hazard. Mater., 164(2-3), 459 (2009)
  16. Patel R, Suresh S, J. Hazard. Mater., 137(3), 1729 (2006)
  17. Zhang H, Duan L, Zhang Y, Wu F, Dyes Pigment., 65, 39 (2005)
  18. Karci A, Chemosphere, 99, 1 (2014)
  19. Nezamzadeh-Ejhieh A, Karimi-Shamsabadi M, Chem. Eng. J., 228, 631 (2013)
  20. Nezamzadeh-Ejhieh A, Khodabakhshi-Chermahini F, J. Ind. Eng. Chem., 20(2), 695 (2014)
  21. Nezamzadeh-Ejhieh A, Moazzeni N, J. Ind. Eng. Chem., 19(5), 1433 (2013)
  22. Nezamzadeh-Ejhieh A, Hushmandrad S, Appl. Catal. A: Gen., 388(1-2), 149 (2010)
  23. Ejhieha AN, Khorsandi M, J. Hazard. Mater., 176(1-3), 629 (2010)
  24. Mook WT, Chakrabarti MH, Aroua MK, Khan GMA, Ali BS, Islam MS, Abu Hassan MA, Desalination, 285, 1 (2012)
  25. Sires I, Brillas E, Environ. Int., 40, 212 (2012)
  26. Ma HZ, Zhuo QF, Wang B, Chem. Eng. J., 155(1-2), 248 (2009)
  27. Kariyajjanavar P, Jogttappa N, Nayaka YA, J. Hazard. Mater., 190(1-3), 952 (2011)
  28. Yang CL, McGarrahan J, J. Hazard. Mater., 127(1-3), 40 (2005)
  29. Parsa JB, Rezaei M, Soleymani AR, J. Hazard. Mater., 168(2-3), 997 (2009)
  30. Can OT, Bayramoglu M, Kobya M, Ind. Eng. Chem. Res., 42(14), 3391 (2003)
  31. Lin SH, Peng CF, Water Res., 28, 277 (2003)
  32. Chen F, Yu S, Dong X, Zhang S, J. Hazard. Mater., 227-228, 474 (2012)
  33. Riera-Torres M, Gutierrez-Bouzan C, Sep. Purif. Methods, 98, 375 (2012)
  34. Liu W, Ai ZH, Zhang LZ, J. Hazard. Mater., 243, 257 (2012)
  35. Farmer JC, Wang FT, Hawley-Fedder RA, Lewis PR, Summers LJ, Foiles L, J. Electrochem. Soc., 139, 654 (1992)
  36. Gu L, Wang B, Ma HZ, Kong WP, J. Hazard. Mater., 137(2), 842 (2006)
  37. Raj NKK, Ramaswamy A, Manikandan P, J. Mol. Catal. A-Chem., 227(1-2), 37 (2005)
  38. Swetha P, Kumar AS, Electrochim. Acta, 98, 54 (2013)
  39. Karimi Z, Mahjoub AR, Aghdam FD, Inorg. Chim. Acta., 362, 3725 (2009)
  40. Kumar SR, Leelavathi P, J. Mol. Catal. A-Chem., 266(1-2), 65 (2007)
  41. Olmez T, J. Hazard. Mater., 162(2-3), 1371 (2009)
  42. Wang J, Chen Y, Ge X, Yu H, Colloids Surf. A: Physicochem. Eng. Asp., 302, 204 (2007)
  43. Wu J, Zhang H, Oturan N, Wang Y, Chen L, Oturan MA, Chemosphere, 87, 614 (2012)
  44. Zhang H, Li Y, Wu X, Zhang Y, Zhang D, Waste Manage., 30, 2096 (2010)
  45. Zhang H, Choi HJ, Canazo P, Huang CP, J. Hazard. Mater., 161(2-3), 1306 (2009)
  46. Rocchiccioli-Deltcheff C, Fournier M, Frank R, Thouvenot R, Inorg. Chem., 22, 207 (1983)
  47. Lu N, Zhao Y, Liu H, Guo Y, Yuan X, Xu H, Peng H, Qin H, J. Hazard. Mater., 199-200, 1 (2012)