Novel microporous hypercross-linked polymers as sorbent for volatile organic compounds and CO2 adsorption

Rajangam Vinodh; Eui Min Jung; Mani Ganesh; Mei Mei Peng; Aziz Abidov; Muthiahpillai Palanichamy; Wang Seog Cha; Hyun Tae Jang

Journal of Industrial and Engineering Chemistry, Vol.21, 1231-1238, January, 2015

DOI10.1016/j.jiec.2014.05.039 Export Citation

Novel microporous hypercross-linked polymers as sorbent for volatile organic compounds and CO2 adsorption

Rajangam Vinodh^{1, 2}, Eui Min Jung^{1, 2}, Mani Ganesh^{1, 2}, Mei Mei Peng^{1, 2}, Aziz Abidov^{1, 2}, Muthiahpillai Palanichamy^{1, 2}, Wang Seog Cha^{2, 3}, and Hyun Tae Jang^{1, 2, †}

¹Department of Chemical Engineering, Hanseo University, Seosan 360-706, South Korea
²Korea Carbon Capture and Sequestration R and D Centre, 360 Daegok-ri, Haemi-myun, Seosan-si 356 706, Chungcheongnam-do, South Korea
³School of Civil and Environmental Engineering, Kunsan National University, Kunsan 573-701, South Korea

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We synthesized highly porous hypercross-linked polymers of (4, 4'-bis ((chloromethyl)-1, 1'-biphenylbenzyl chloride)) [designated as HCP-BCMB] and (1, 3, 5-triphenyl benzene-1, 4-bis (chloromethyl) benzene) [designated as HCP-TPB] as sorbents for the removal of volatile organic compounds such as chloroform, toluene and ethyl methyl ketone under humidified conditions. The micro-porous nature of the hypercross-linked polymers (pore diameter 0.8 nm) was confirmed by Brunner-Emmet-Teller (BET) and scanning electron microscopy (SEM) techniques. HCP-TPB showed a maximum adsorption of 32.8 wt% for toluene. In addition, both the HCPs exhibited CO2 adsorption close to 6 wt% at 25 ℃ and 1 atm.

Keywords:Hypercross-linked polymers;Volatile organic compounds;Adsorption;Friedel-Crafts reaction;Quinonoid chromophores

[References]

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Tam BN, Neumann CM, J. Environ. Manage., 73, 131 (2004)
Schaich RJ, Chem. Eng. Prog., 87, 31 (1991)
Seinfeld JH, Pandis SN, Atmospheric Chemistry and Physics From Air Pollution to Climate Change, 1st ed., J. Wiley, New York, 1998.
Gupta VK, Verma N, Chem. Eng. Sci., 57(14), 2679 (2002)
Kosuge K, Kubo S, Kikukawa N, Takemori M, Langmuir, 23(6), 3095 (2007)
Ikram J, Sophie F, Mourad B, Samir B, Chem. Geol., 275, 1 (2010)
Serrano DP, Calleja G, Botas JA, Gutierrez FJ, Ind. Eng. Chem. Res., 43(22), 7010 (2004)
Lu CY, Wey MY, Fuel Process. Technol., 88(6), 557 (2007)
Yang K, Sun Q, Xue F, Lin DH, J. Hazard. Mater., 195, 124 (2011)
Jones LA, Ott A, Tardio J, Morrison P, Rosenberg S, Gunda M, Bhargava SK, J. Environ. Chem. Eng., 2, 626 (2014)
Chu YH, Kim HJ, Song KY, Shul YG, Jung KT, Lee K, Han MH, Catal. Today, 74(3-4), 249 (2002)
Lopez-Fonseca R, de Rivas B, Gutierrez-Ortiz JI, Aranzabal A, Gonzalez-Velasco JR, Appl. Catal. B: Environ., 41(1-2), 31 (2003)
Tsyurupa MP, Davankov VA, React. Funct. Polym., 66(7), 768 (2006)
Vinodh R, Hemalatha P, Ganesh M, Peng MM, Abidov A, Palanichamy M, Cha WS, Jang HT, RSC Adv., 4, 3668 (2014)
Okay O, Prog. Polym. Sci, 25, 711 (2000)
Gokmen MT, DuPrez EF, Prog. Polym. Sci, 37, 365 (2012)
Duranoglu D, Kaya IG, Beker U, Senkal BF, Chem. Eng. J., 103, 181 (2012)
Huang JH, Yang L, Wu XF, Xu MW, Liu YN, Deng SG, Chem. Eng. J., 222, 1 (2013)
Xu SJ, Luo YL, Tan BE, Macromol. Rapid Commun., 34(6), 471 (2013)
Wu DC, Xu F, Sun B, Fu RW, He HK, Matyjaszewski K, Chem. Rev., 112(7), 3959 (2012)
He H, Li W, Zhong M, Konkolewicz D, Wu D, Yaccato K, Rappold T, Sugar G, David NE, Matyjaszewski K, Energy Environ. Sci., 6, 488 (2013)
Long C, Liu P, Li Y, Li A, Zhang Q, Environ. Sci. Technol., 45, 4506 (2011)
Tsyurupa MP, Davankov VA, React. Funct. Polym., 53(2-3), 193 (2002)
Fontanals N, Galia M, Cormack PAG, Marce RM, Sherrington DC, Borrull F, J. Chromatogr. A, 1075, 51 (2005)
Valderrama C, Gamisans X, Heras FXDL, Cortina JL, Farran A, React. Funct. Polym., 67(12), 1515 (2007)
Long C, Li A, Wu H, Zhang Q, Colloids Surf. A: Physicochem. Eng. Asp., 333, 150 (2009)
Podlesnyuk VV, Hradil J, Kralova E, React. Funct. Polym., 42(3), 181 (1999)
Simpson EJ, Koros WJ, Schechter RS, Ind. Eng. Chem. Res., 35(12), 4635 (1996)
Meng QB, Yang GS, Lee YS, Microporous Mesoporous Mater., 181, 222 (2013)
Meng QB, Yang GS, Lee YS, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.10.030.
Long C, Li QF, Li Y, Liu YA, Li AM, Zhang QX, Chem. Eng. J., 160(2), 723 (2010)
Liu P, Long C, Li QF, Qian HM, Li AM, Zhang QX, J. Hazard. Mater., 166(1), 46 (2009)
Abdollahi S, Mostaghni F, Int. J. Mater. Chem., 2, 128 (2012)
Vinodh R, Kim DK, Hwang Y, Yeo HG, Int. J. Biosci. Biotechnol., 5, 85 (2013)
Zhang X, Jin Q, Dai L, Yuan S, Bull. Mater. Sci., 34, 735 (2011)
Gupta KN, Rao NJ, Agarwal GK, Int. J. Chem. Eng. Appl., 2, 310 (2011)

[Referenced By]

[1] Hunt WF, Faoro RB, Freas W, Interim Database for State and Local Air Toxic Volatile Organic Chemical Measurements, (Tech. Rep. PB-87-168779/XAB; EPA-450/4-86/012), 1986.

[2] Tam BN, Neumann CM, J. Environ. Manage., 73, 131 (2004)

[3] Schaich RJ, Chem. Eng. Prog., 87, 31 (1991)

[4] Seinfeld JH, Pandis SN, Atmospheric Chemistry and Physics From Air Pollution to Climate Change, 1st ed., J. Wiley, New York, 1998.

[5] Gupta VK, Verma N, Chem. Eng. Sci., 57(14), 2679 (2002)

[6] Kosuge K, Kubo S, Kikukawa N, Takemori M, Langmuir, 23(6), 3095 (2007)

[7] Ikram J, Sophie F, Mourad B, Samir B, Chem. Geol., 275, 1 (2010)

[8] Serrano DP, Calleja G, Botas JA, Gutierrez FJ, Ind. Eng. Chem. Res., 43(22), 7010 (2004)

[9] Lu CY, Wey MY, Fuel Process. Technol., 88(6), 557 (2007)

[10] Yang K, Sun Q, Xue F, Lin DH, J. Hazard. Mater., 195, 124 (2011)

[11] Jones LA, Ott A, Tardio J, Morrison P, Rosenberg S, Gunda M, Bhargava SK, J. Environ. Chem. Eng., 2, 626 (2014)

[12] Chu YH, Kim HJ, Song KY, Shul YG, Jung KT, Lee K, Han MH, Catal. Today, 74(3-4), 249 (2002)

[13] Lopez-Fonseca R, de Rivas B, Gutierrez-Ortiz JI, Aranzabal A, Gonzalez-Velasco JR, Appl. Catal. B: Environ., 41(1-2), 31 (2003)

[14] Tsyurupa MP, Davankov VA, React. Funct. Polym., 66(7), 768 (2006)

[15] Vinodh R, Hemalatha P, Ganesh M, Peng MM, Abidov A, Palanichamy M, Cha WS, Jang HT, RSC Adv., 4, 3668 (2014)

[16] Okay O, Prog. Polym. Sci, 25, 711 (2000)

[17] Gokmen MT, DuPrez EF, Prog. Polym. Sci, 37, 365 (2012)

[18] Duranoglu D, Kaya IG, Beker U, Senkal BF, Chem. Eng. J., 103, 181 (2012)

[19] Huang JH, Yang L, Wu XF, Xu MW, Liu YN, Deng SG, Chem. Eng. J., 222, 1 (2013)

[20] Xu SJ, Luo YL, Tan BE, Macromol. Rapid Commun., 34(6), 471 (2013)

[21] Wu DC, Xu F, Sun B, Fu RW, He HK, Matyjaszewski K, Chem. Rev., 112(7), 3959 (2012)

[22] He H, Li W, Zhong M, Konkolewicz D, Wu D, Yaccato K, Rappold T, Sugar G, David NE, Matyjaszewski K, Energy Environ. Sci., 6, 488 (2013)

[23] Long C, Liu P, Li Y, Li A, Zhang Q, Environ. Sci. Technol., 45, 4506 (2011)

[24] Tsyurupa MP, Davankov VA, React. Funct. Polym., 53(2-3), 193 (2002)

[25] Fontanals N, Galia M, Cormack PAG, Marce RM, Sherrington DC, Borrull F, J. Chromatogr. A, 1075, 51 (2005)

[26] Valderrama C, Gamisans X, Heras FXDL, Cortina JL, Farran A, React. Funct. Polym., 67(12), 1515 (2007)

[27] Long C, Li A, Wu H, Zhang Q, Colloids Surf. A: Physicochem. Eng. Asp., 333, 150 (2009)

[28] Podlesnyuk VV, Hradil J, Kralova E, React. Funct. Polym., 42(3), 181 (1999)

[29] Simpson EJ, Koros WJ, Schechter RS, Ind. Eng. Chem. Res., 35(12), 4635 (1996)

[30] Meng QB, Yang GS, Lee YS, Microporous Mesoporous Mater., 181, 222 (2013)

[31] Meng QB, Yang GS, Lee YS, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.10.030.

[32] Long C, Li QF, Li Y, Liu YA, Li AM, Zhang QX, Chem. Eng. J., 160(2), 723 (2010)

[33] Liu P, Long C, Li QF, Qian HM, Li AM, Zhang QX, J. Hazard. Mater., 166(1), 46 (2009)

[34] Abdollahi S, Mostaghni F, Int. J. Mater. Chem., 2, 128 (2012)

[35] Vinodh R, Kim DK, Hwang Y, Yeo HG, Int. J. Biosci. Biotechnol., 5, 85 (2013)

[36] Zhang X, Jin Q, Dai L, Yuan S, Bull. Mater. Sci., 34, 735 (2011)

[37] Gupta KN, Rao NJ, Agarwal GK, Int. J. Chem. Eng. Appl., 2, 310 (2011)