화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 1417-1422, January, 2015
DOI10.1016/j.jiec.2014.06.016  Export Citation
Synthesis and characterization of phenol-formaldehyde resin using enzymatic hydrolysis lignin
Wei Qiao, Shujun Li†, Guowan Guo, Shiyan Han, Shixue Ren, and Yanli Ma
  • Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, PR China
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Enzymatic hydrolysis lignin (EHL) was utilized to partially replace phenol for preparing phenolformaldehyde (PF) resin. The influence of lignin substitution rate on the properties of the lignin-modified phenol-formaldehyde (LPF) resin was investigated. Lignin substitution of 60 wt% did not deteriorate the adhesive strength of PF resin. FTIR analysis of the resins revealed that the incorporation of EHL made no big difference in chemical structure, but led to a deteriorated thermal resistance. The comparison between LPF and bio-ethanol production residue-modified phenol-formaldehyde (RPF) resins elucidated that the purification processwas beneficial for its higher substitution application and better performance of adhesive.
Keywords:Enzymatic hydrolysis lignin;Phenol-formaldehyde resin;Adhesive strength;Microstructure;Purification
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