Nb이 첨가된 Ti합금의 내식성 및 생체안정성

이도재; 이광민; 이경구; 유창남; 오태욱; 김수학; 윤택림; Doh-Jae Lee; Kwang-Min Lee; Kyung-Ku Lee; Chang-Nam Ryu; Tae-Wook Oh; Soo-Hag Kim; Tack-Lim Yoon

Korean Journal of Materials Research, Vol.13, No.11, 761-768, November, 2003

DOI10.3740/MRSK.2003.13.11.761 Export Citation

Nb이 첨가된 Ti합금의 내식성 및 생체안정성

Effects of Nb Addition on Corrosion Resistance and Cytotoxicity Behavior of Ti Alloys

이도재, 이광민, 이경구, 유창남, 오태욱^†, 김수학, 윤택림¹

전남대학교 공과대학 신소재공학부
¹전남대학교 의과대학 정형외과

Doh-Jae Lee, Kwang-Min Lee, Kyung-Ku Lee, Chang-Nam Ryu, Tae-Wook Oh^†, Soo-Hag Kim, and Tack-Lim Yoon¹

Dept. of Materials Science and Engineering, Chonnam National University, Korea
¹Dept. of Orthopedics Surgery, Chonnam National University, Korea

E-mail:

The corrosion resistance and cytotoxicity behavior of Ti alloys were studied as a function of Nb contents(3wt.%Nb, 20wt.%Nb, 40wt.%Nb). Ti-Nb alloys were melted by vacuum arc furnace and then rolled to 50% reduction ratio after homogenized at 105 for 24hrs. The corrosion resistance of Ti-Nb alloys were investigated by potentiodynamic polarization test in the 0.9% NaCl and 5% HCI solution. Biocompatibility of Ti-Nb alloys was evaluated by cytotoxicity test. The results can be summarized as follows 1) The microstructure change from equiaxial to acicular and the increased phase in Ti-Nb alloys were obtained as the Nb content increased. 2) For the corrosion test in the solution of 0.9% NaCl and 5% HCI, the corrosion behavior of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 3) For the cytotoxicity test, Ti-Nb alloys showed excellent biocompatibility compared to ASTM grade 2 CP Ti, 316L STS and Co-Cr alloys.

Keywords:titanium;Ti-Nb;cytotoxicity;biocompatibility;corrosion resistance

[References]

Okazaki Y, Kyo K, Ito Y, Tateishi T, J. Japan Inst. Metals, 59(10), 1061 (1995)
Ahmed T, Long M, Silvestri J, Ruiz C, Rack HJ, Titanium 95 science and technology, 2, 1760 (1995)
Steinemann SG, Evalution of Biomaterials, John Wiley & Sons Ltd., 1 (1980) (1980)
Davidson JA, Mishira AK, Poggie RA, Biomed. Mat. Eng., 4, 231 (1994)
Yumoto S, et al., International Journal of PIXE, World scientific Publishing Company, 2(4) 493 (1992) (1992)
Cheal EJ, Spector M, Hayes WC, Clin. Orthop. Relat. Res., 10, 405 (1992)
Prendergast PJ, Taylor D, J. Biomed Eng., 12, 379 (1990)
Huiskes R, Harrie Weinans and Bert Van Rietbergen, Clin Orthop Relat Res., 274, 124 (1992) (1992)
Engh CA, Bobyn JD, Clin Orthop Relat Res., 231, 7 (1988)
Murrary JL, Bennett LH, Backer H, Binary Alloy Phase Diagrams, American society for metals, (1986) (1986)
Allameh SM, Hayes RW, Li M, Loria EA, Srolovitz DJ, Soboyejo WO, Mater. Sci. Eng. A, 328, 122 (2002)
Daeubler MA, Helm D, Lutjering G, Titanium '95: Science and Technology, 709 (1995)
Cho HJ, Lee JH, K. J, Mater. Res., 4, 626 (1994)
Kasemo B, Lausmaa, J. Biomaterial and implant surfaces: A surface science approach. Int J Oral Maxillofacial Implants, 3, 247 (1988)
McAlamey ME, Oshiro MA, McAlarney CV, Effect of titanium dioxide passive film crystal structure, thickness, and crystallinity on C# adsorption. Int J Oral Maxillofac Implants, 11, 73-80 (1996) (1996)
Yu SY, Scully JR, Corrosion, 53(12), 965 (1997)
Akahori T, Niinomi M, Mater. Sci. Eng. A, 243, 237 (1998)
Lausmaa J, J. electron spectroscopy, 81, 343 (1996)

[Referenced By]

[1] Okazaki Y, Kyo K, Ito Y, Tateishi T, J. Japan Inst. Metals, 59(10), 1061 (1995)

[2] Ahmed T, Long M, Silvestri J, Ruiz C, Rack HJ, Titanium 95 science and technology, 2, 1760 (1995)

[3] Steinemann SG, Evalution of Biomaterials, John Wiley & Sons Ltd., 1 (1980) (1980)

[4] Davidson JA, Mishira AK, Poggie RA, Biomed. Mat. Eng., 4, 231 (1994)

[5] Yumoto S, et al., International Journal of PIXE, World scientific Publishing Company, 2(4) 493 (1992) (1992)

[6] Cheal EJ, Spector M, Hayes WC, Clin. Orthop. Relat. Res., 10, 405 (1992)

[7] Prendergast PJ, Taylor D, J. Biomed Eng., 12, 379 (1990)

[8] Huiskes R, Harrie Weinans and Bert Van Rietbergen, Clin Orthop Relat Res., 274, 124 (1992) (1992)

[9] Engh CA, Bobyn JD, Clin Orthop Relat Res., 231, 7 (1988)

[10] Murrary JL, Bennett LH, Backer H, Binary Alloy Phase Diagrams, American society for metals, (1986) (1986)

[11] Allameh SM, Hayes RW, Li M, Loria EA, Srolovitz DJ, Soboyejo WO, Mater. Sci. Eng. A, 328, 122 (2002)

[12] Daeubler MA, Helm D, Lutjering G, Titanium '95: Science and Technology, 709 (1995)

[13] Cho HJ, Lee JH, K. J, Mater. Res., 4, 626 (1994)

[14] Kasemo B, Lausmaa, J. Biomaterial and implant surfaces: A surface science approach. Int J Oral Maxillofacial Implants, 3, 247 (1988)

[15] McAlamey ME, Oshiro MA, McAlarney CV, Effect of titanium dioxide passive film crystal structure, thickness, and crystallinity on C# adsorption. Int J Oral Maxillofac Implants, 11, 73-80 (1996) (1996)

[16] Yu SY, Scully JR, Corrosion, 53(12), 965 (1997)

[17] Akahori T, Niinomi M, Mater. Sci. Eng. A, 243, 237 (1998)

[18] Lausmaa J, J. electron spectroscopy, 81, 343 (1996)