Spark Plasma Sintering을 이용한 Cu-26.7Zn-4.05Al(wt.%) 형상기억합금의 제조

박노진; 이인성; 조경식; 김성진; No-Jin Park; In-Sung Lee; Kyeong-Sik Cho; SungJin Kim

Korean Journal of Materials Research, Vol.13, No.6, 352-359, June, 2003

DOI10.3740/MRSK.2003.13.6.352 Export Citation

Spark Plasma Sintering을 이용한 Cu-26.7Zn-4.05Al(wt.%) 형상기억합금의 제조

Manufacturing of Cu-26.7Zn-4.05Al(wt.%) Shape Memory Alloy Using Spark Plasma Sintering

박노진 ^†, 이인성, 조경식 , 김성진

금오공과대학교 신소재시스템공학부

No-Jin Park^†, In-Sung Lee, Kyeong-Sik Cho , and SungJin Kim

School of Advanced Materials and Systems Engineering, Kumoh National Institute of Technology, 188 Shinpyung-dong, Gumi 730-701, Korea

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In order to control the grain size, the spark plasma sintering technique is applied for the manufacturing of Cu-26.7Al-4.05AI(wt.%) shape memory alloy with pure Cu, Zn, and Al element powders. The sintering processes were carried out under different atmospheres. The sintered bodies were denser under Ar or Ar+4% H 2 gas atmosphere than under vacuum. With use of small-sized powders, a very small average grain size of 2∼3 μm was obtained, but the single phase was not formed. With the large-sized powders the single austenitic phase was observed with the average grain size of 70∼72μm . When the different size of raw powders was mixed, it is confirmed that the average grain size of the manufactured alloys was 15 μm with single austenitic phase, but the distribution of grain size was not uniform.

Keywords:SPS(spark plasma sintering);shape memory alloy;powder metallurgy;CuZnAl alloy;grain refinement

[References]

Duering TW, Melton KN, Stoeckel D, Wayman CM 'Engineering Aspects of Shape Memory Alloys' , Butterworth-Heinemann Ltd, London (1990) (1990)
Nishiyama Z, Martensitic Transformation, Academic Press (1978) (1978)
Lee JS, Wayman CM, Metallographie, 19, 401 (1986)
Murakami K, Murakami Y, Mishma K, Ikai Y, J. Japan Int. Metals, 48, 115 (1984)
Choi CS, Chung IS, J. Korean. Inst. Met. & Mater., 34, 680 (1996)
Janssen J, Willems F, Verelst B, J. de Physique, 43, C4 (1982)
Nakanishi N, Shigematsu T, Bull. Japan Int. Metals, 28, 659 (1989)
Choi YT, Chung IS, J. Korean Inst. Met. & Mater., 28, 857 (1990)
Park NJ, Wang CQ, Bunge HJ, Mat. Sci. Forum, 157-162, 827 (1994)
Yi SB, Park NJ, Korean J. Materials Research, 9, 322 (1999)
Tokita M, J. Powder Tech. Japan., 30, 790 (1993)
Cho KS, Kim S, Beak SH, Choi HJ, Lee JG, J. Kor. Ceram. Soc., 38, 687 (2001)
lyama M, et al., Abstracts of 1999 annual meeting of JSPM, 237 (1999) (1999)
Muraoka T, Asaoka T, Abstracts of 1999 annual meeting of JSPM, 238 (1999)
Park NJ, Lee IS, Cho KS, Kim S, Crystal Growth and Crystal Technology, 12, 172 (2002)
Delaey L, Deruyttere A, Aernoudt E, Roos JR, Shape Memory Effect, Superelasticity and Damping in Copper-Zinc-Aluminium Alloys, INCRA Report 78R1, Belgium, (1978) (1978)
Villas P, Prince A, Okamoto H, Handbook of Ternary Alloy Phase Diagrams, ASM International, 3, (1990) (1990)
Delaey L, De Vos R, Z. Metallkde., 70, 33 (1979)

[Related Articles]

[1] Duering TW, Melton KN, Stoeckel D, Wayman CM 'Engineering Aspects of Shape Memory Alloys' , Butterworth-Heinemann Ltd, London (1990) (1990)

[2] Nishiyama Z, Martensitic Transformation, Academic Press (1978) (1978)

[3] Lee JS, Wayman CM, Metallographie, 19, 401 (1986)

[4] Murakami K, Murakami Y, Mishma K, Ikai Y, J. Japan Int. Metals, 48, 115 (1984)

[5] Choi CS, Chung IS, J. Korean. Inst. Met. & Mater., 34, 680 (1996)

[6] Janssen J, Willems F, Verelst B, J. de Physique, 43, C4 (1982)

[7] Nakanishi N, Shigematsu T, Bull. Japan Int. Metals, 28, 659 (1989)

[8] Choi YT, Chung IS, J. Korean Inst. Met. & Mater., 28, 857 (1990)

[9] Park NJ, Wang CQ, Bunge HJ, Mat. Sci. Forum, 157-162, 827 (1994)

[10] Yi SB, Park NJ, Korean J. Materials Research, 9, 322 (1999)

[11] Tokita M, J. Powder Tech. Japan., 30, 790 (1993)

[12] Cho KS, Kim S, Beak SH, Choi HJ, Lee JG, J. Kor. Ceram. Soc., 38, 687 (2001)

[13] lyama M, et al., Abstracts of 1999 annual meeting of JSPM, 237 (1999) (1999)

[14] Muraoka T, Asaoka T, Abstracts of 1999 annual meeting of JSPM, 238 (1999)

[15] Park NJ, Lee IS, Cho KS, Kim S, Crystal Growth and Crystal Technology, 12, 172 (2002)

[16] Delaey L, Deruyttere A, Aernoudt E, Roos JR, Shape Memory Effect, Superelasticity and Damping in Copper-Zinc-Aluminium Alloys, INCRA Report 78R1, Belgium, (1978) (1978)

[17] Villas P, Prince A, Okamoto H, Handbook of Ternary Alloy Phase Diagrams, ASM International, 3, (1990) (1990)

[18] Delaey L, De Vos R, Z. Metallkde., 70, 33 (1979)