화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.13, No.6, 404-408, June, 2003
테트라메틸사일렌을 이용한 탄화규소 나노로드의 성장
Growth of SiC Nanorod Using Tetramethylsilane
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SiC nanorods have been grown on Si (100) substrate directly. Tetramethylsilane and Ni were used for SiC nanorod growth. After 3minute, SiC nanorod had grown by CVD. Growth regions ware divided by two regions with diameter. The First region consisted of thin SiC nanorods having below 10 nm diameter, but second region's diameter was 10∼50 nm. This appearance shows by reduction of growth rate. The effect of temperature and growth time was investigated by scanning electron microscopy. Growth temperature and time affected nanorod's diameter and morphology. With increasing growth time, nanorod's diameter increased because of the deactivation effect. But growth temperatures affected little. By TEM characterization, grown SiC nanorods consisted of the polycrystalline grain.
  1. Dillon AC, Jones KM, Bekkedahl TA, Kiang CH, Bethune DS, Heben MJ, Nature, 386(6623), 377 (1997)
  2. Gadd GE, Blackford M, Moricca S, Webb N, Evans PJ, Smith AN, Jacobsen G, Leung S, Day A, Hua Q, Science, 277(5328), 933 (1997)
  3. Boo JH, Yu KS, Kim Y, Yeon SH, Jung JN, Chem. Mater, 7, 694 (1995)
  4. Dai HJ, Wong EW, Lu YZ, Fan SS, Lieber CM, Nature, 375(6534), 769 (1995)
  5. Meng GW, Zhang LS, Mo CM, Phillip F, Qin Y, Li HJ, Feng SP, Zhang SY, Mater. Res. Bull., 34(5), 783 (1999)
  6. Tang CC, Fan SS, Dang HY, Zhao JH, Zhang C, Li P, Gu Q, J. Crystal Growth, 223, 125 (2001)
  7. Li Y, Xie S, Wei B, Lian G, Zhou W, Tang D, Zou X, Weng G, Solid State Communications, 119, 51 (2001)
  8. Li YB, Xie SS, Zou XP, Tang DS, Liu ZQ, Zhou WY, Wang G, J. Cryst. Growth, 223(1-2), 125 (2001)
  9. Zhang Y, Wang NL, He R, Chen X, Zhu J, Solid State Communications, 118, 595 (2001)
  10. Meng GW, Zhang LD, Mo CM, Zhang SY, Li HJ, Qin Y, Feng SP, Metal. Mat. Trans. A, 30A, 213 (1999)
  11. Wu XC, Song WH, Huang WD, Pu MH, Zhao B, Sun YP, Du JJ, Mater. Res. Bull., 36(5-6), 847 (2001)
  12. Ishizaka A, Shiraki Y, J. Electrochem. Soc., 133, 666 (1986)
  13. Pan ZW, Xie SS, Sun LF, Wang G, Chem Phys. Lett., 299, 97 (1999)
  14. Lee CJ, Park JH, Park J, Chem. Phys. Lett., 323(5-6), 560 (2000)
  15. Lahaye J, Badie D, J. Ducret, Carbon, 15, 87 (1977)