In this paper the results of an on-site experimental analysis carried out on a Molten Carbonate Fuel Cell (MCFC) fed by different fuels (hydrogen, landfill gas and different mixtures of them) are presented. The examined MCFC is one of the experimental devices of an innovative power plant located at the urban landfill of Giugliano in Campania (Naples, Italy). Here, electricity is produced through four cogenerative reciprocating engines and one cogenerative gas turbine fed by landfill gas, operating since 2003. At the same site, two different fuel cells are installed for scientific purposes. During the considered experimental campaign, the MCFC is initially supplied by hydrogen for testing the system at the best operating conditions. Afterward, the fuel cell is fed by mixtures of different ratios of hydrogen and reformed landfill gas. For this reason, the system is equipped with an external reformer and a suitable gas cleaning. In order to analyse the system energy performance under varying electricity loads (obtained through an electronic device), several tests were carried out. In addition, several stress tests were also performed aiming at analysing the system endurance when fed by landfill gas. The experimental results concerning the produced electric currents and voltages show satisfactory performance of the system, while the obtained operating temperatures and cell reliability still need to be improved. (C) 2014 Elsevier Ltd. All rights reserved.