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Journal of Electroanalytical Chemistry, Vol.391, No.1-2, 1-10, 1995
Electric-Field Effects on the Structure and Dynamics at a Liquid-Vertical-Bar-Liquid Interface
The structure and dynamics of the water1,2-dichloroethane interface under the influence of a static electric field are studied using molecular dynamics computer simulation. By calculating global structural features such as density profiles, interface width, total energies and interfacial tension, we show that the electric field tends to broaden the interface and decrease the surface tension by increasing the amplitude of finger-like distortions without strongly affecting the local microscopic structure or dynamics.
Keywords:OIL-WATER INTERFACE;MOLECULAR-DYNAMICS;ION TRANSFER;SIMULATION;ADSORPTION;GENERATION;KINETICS