화학공학소재연구정보센터
Chemical Physics Letters, Vol.609, 65-69, 2014
'Unsticking' and exposing the surface area of graphene bilayers via randomly distributed nanoparticles
The exemplary properties of graphene and the potential inclusion of nanoparticles have suggested applications in energy storage, catalysts and sensing. A critical feature of the performance of these nanocomposites is the distribution of nanoparticles and the exposed area of the graphene. Here we report a computational analysis exploring the effect of the dispersion of nanoparticles between layers of graphene, characterizing both solvent accessible surface area (SASA) and inter-graphene adhesion energy (Delta E-g). We find a maximum number of nanoparticles before the accessible graphene surface area decreases, and a limit where the system separates as the graphene layers no longer 'stick'. (C) 2014 Elsevier B.V. All rights reserved.