We describe preparation and characterization of nanostructured electrodes using Co(OH)(2) nano-flakes and carbon fiber cloth for supercapacitors. Nanostructured Co(OH)(2) flakes are produced by electrodeposition and they are coated onto the electro-etched carbon fiber cloth. A highest specific capacitance of 3404.8 Fg(-1) and an area-normalized specific capacitance of 3.3 Fcm(-2) have been obtained from such electrodes. Morphology and structure of the nanostructured electrodes have been characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical properties have been studied by cyclic voltammetry (CV), constant-current charge and discharge, electrochemical impedance spectroscopy (EIS), and long-time cycling. (C) 2014 Elsevier B.V. All rights reserved.