화학공학소재연구정보센터
Electrochimica Acta, Vol.153, 361-369, 2015
An Oriented Ultrathin Catalyst Layer Derived from High Conductive TiO2 Nanotube for Polymer Electrolyte Membrane Fuel Cell
An oriented ultrathin catalyst layer (UTCL) has been prepared for fuel cells application based on the high electrical conductivity TiO2 nanotube (TNTs). The electrical conductivity of TNTs was improved by the deposited C via a plasma enhanced chemical vapor deposition (PECVD) technique. Pt catalysts were deposited on the high electrical conductivitve TNTs by the radio frequency (RF) sputtering to form the oriented C-TNTs-Pt electrode. The mass activity of C-TNTs-Pt-1 at 0.85V was about 0.44 A mg(Pt)(-1). The prepared oriented UTCL based on the C-TNTs-Pt electrode displayed a maximum power density of 206 and 305 mWcm(-2) at an ultralow Pt loading resulting in a relatively high Pt utilization of 8.3 and 6.0 kW g(Pt)(-1). A 2D symmetry model based on the parameters of the oriented UTCL was established. In the model, the performance of fuel cell was improved along with the decreasing of CL thickness. Meanwhile, it is found that there is little effect on the cell performance when the electrical conductivity of CL is larger than 3 Scm(-1). The study in this work gave effectual evidence on the possibility of using the oriented UTCL for developing low cost fuel cells. (C) 2014 Elsevier Ltd. All rights reserved.