An investigation of the surface properties related to the method of microelectrode fabrication is presented and discussed. The voltammetric response in acidic media (sulphuric and formic acids) of fractured 25 mu m diameter wire which had been sealed in soft glass was used to investigate the surface microstructure. SEM studies showed that the crystallite size of the fractured wire, which had previously been sealed in glass, was large, and that a single crystallite may be exposed to the solution surface. The effect of sealing the wire in glass on the bulk properties of the wire is related to the voltammetric response in acid media. Thus, the surface of a polished platinum microelectrode sealed in glass cannot be considered as truly polycrystalline. The responses of fractured platinum wire sealed in soft glass in sulphuric acid and formic acid are predominantly Pt(111), when compared by non-linear regression and congruent analysis with the three low index faces of platinum in the same acidic medium under the same conditions. This is explained by the process of slip deformation, which involves the slipping of Pt(111) planes (close packed planes or planes of highest atomic density) forming steps with the exposed surface predominantly Pt(111).