Inorganic Chemistry, Vol.53, No.19, 10009-10011, 2014
High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex
The six-coordinate cobalt(II) complex of formula [Co(tppz)(2)](tcm)(2) exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K