The capacity of hydrogen storage for solid sorbents depends strongly on the binding affinity between hydrogen molecules and solid sorbents. By coating C-60 with a low ionization energy material (Li2F), we obtained an enhanced binding energy and an improved electron transfer between H-2 and hosts. With the first-principles calculations and charge analysis, we found that the orbital interactions play a dominant role in this system and eventually 68H(2) molecules can be stably stored by a C-60(Li2F)(12) cluster with a binding energy of 0.12 eV/H-2. The resulting gravimetric and volumetric density of H-2 stored on C-60(Li2F)(12) are 10.86 wt % and the 59 g/L through calculations. Our investigation indicates that metals or metal clusters with lower ionization energies would be beneficial to enhance interactions between hydrogen and hosts, and thus, the hydrogen storage capacities for solid sorbents can be greatly improved. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.