A series of nitrogen-doped graphene nanocomposites (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites with varied mass ratio between GO and aniline were used as support for immobilization of Pt nanoparticles. Transmission electron microscopy, X-ray powder diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy were used to characterize the morphology and microstructure of the prepared catalysts. The catalytic activity of the catalysts towards the oxidation of methanol was evaluated by cyclic voltammetry. Compared to the undoped Pt/RGO catalyst, an enhanced electrocatalytic activity for methanol oxidation was obtained in the case of the Pt/N-RGO with optimized composition and nanostructure. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.