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Journal of Chemical Thermodynamics, Vol.80, 172-183, 2015
Thermodynamic modeling of high salinary phosphate solutions II. Ternary and higher systems
A comprehensive set of ternary interaction Pitzer parameters for solutions of the system Na-K-Cl-SO4-PO4-HPO4-H2PO4 was calculated from water activity and solubility data acquired from an extensive literature review and water activity data obtained from isopiestic experiments. This work is a continuation of part I, wherein results concerning binary phosphate systems are presented. (C) 2014 Elsevier Ltd. All rights reserved.
Keywords:Phosphate solutions;Pitzer parameters;Isopiestic;Solubility;Thermodynamic data base;Nuclear waste disposal;Water activity