화학공학소재연구정보센터
Journal of Crystal Growth, Vol.407, 6-10, 2014
Defect reduction of SiNx embedded m-plane GaN grown by hydride vapor phase epitaxy
Nonpolar (1 0 - 1 0) m-plane GaN has been grown on m-plane sapphire substrates by hydride vapor phase epitaxy (HVPE). We studied the defect reduction of m-GaN with embedded SiNx, interlayers deposited by ex-situ metal organic chemical vapor deposition (MOCVD). The full-width at half-maximum values of the X-ray rocking curves for m-GaN with embedded SiNx along [1 1 - 2 0](GaN) and [0 0 0 1](GaN) were reduced to 528 and 1427 arcs, respectively, as compared with the respective values of 947 and 3170 arcs, of m-GaN without SiNx. Cross-section transmission electron microscopy revealed that the basal stacking fault density was decreased by approximately one order to 5 x 10(4) cm(-1) due to the defect blocking of the embedded SiNx. As a result, the near band edge emission intensities of the room-temperature and low-temperature photoluminescence showed approximately two-fold and four-fold improvement, respectively. (C) 2014 Elsevier B.V. All rights reserved.