화학공학소재연구정보센터
Journal of Crystal Growth, Vol.411, 30-33, 2015
Measurement of the diffusivity of CdTe in liquid Te at crystal growth temperatures
The diffusivity of CdTe in tellurium-rich liquid solution was measured by dissolving solid samples at temperatures applicable to THM crystal growth. We calculated the resulting diffusion coefficients to be 0.008 mm(2)/s at 850 degrees C and 0.009 mm(2)/s at 900 degrees C. The CdTe was dissolved under isothermal conditions in 7 mm diameter quartz tubes for 45 min, 90 min and 180 min. The diffusivity was calculated from the distance travelled by the dissolution interface using a 1D transport model. Measurement of the solution composition by EDS confirms that the experiments were diffusion-dominated, and the calculated diffusivities match those predicted elsewhere ab initio for similar conditions. (C) 2014 Elsevier B.V. All rights reserved.