Palladium nanoparticles encapsulated in a dendrimer networks as catalysts for the hydrogenation of unsaturated hydrocarbons

Karakhanov EA; Maksimov AL; Zakharian EM; Kardasheva YS; Savilov SV; Truhmanova NI; Ivanov AO; Vinokurov VA

Journal of Molecular Catalysis A-Chemical, Vol.397, 1-18, 2015

DOI10.1016/j.molcata.2014.10.018 Export Citation

Palladium nanoparticles encapsulated in a dendrimer networks as catalysts for the hydrogenation of unsaturated hydrocarbons

Karakhanov EA, Maksimov AL, Zakharian EM, Kardasheva YS, Savilov SV, Truhmanova NI, Ivanov AO, Vinokurov VA

A novel method has been proposed for encapsulating palladium nanoparticles up to 5 nm in the matrix of polymeric support networks based on polyamidoamine dendrimers. The shape of the particle size distribution and the catalytic activity of the materials obtained during the hydrogenation of unsaturated compounds depend strongly on the support structure. High activity (TOF up to 86,000 h(-1)) has been observed during the hydrogenation of styrene. (C) 2014 Elsevier B.V. All rights reserved.

Keywords:Pd catalysts;Nanoparticles;PAMAM dendrimer;Selective hydrogenation