Journal of Polymer Science Part B: Polymer Physics, Vol.52, No.19, 1276-1282, 2014
A Study of the Yield and Post-Yield Behavior of Syndiotactic Polypropylene
The strain recovery of three syndiotactic polypropylenes (s-PPs) differing in the percentage of [rrrr] pentad is investigated. A suitable method based on loading-unloading tests at constant displacement rate in tensile loading conditions is adopted to measure the residual and recovered strain components of the applied strain. The method allows to obtain a large amount of data from few tests and to explore a wide strain range. The dependence of the material's strain recovery on the applied strain is analyzed in relation to s-PP strain-induced microstructural changes and crystalline form transitions, which are reported in literature. (C) 2014 Wiley Periodicals, Inc.