Three-dimensional (3D) multilayer porous MnO2/reduced graphene oxide composites are coated on a nickel foam substrate (denoted as MnO2/R-GO@Ni-foam) by a facile and scalable spray method following by low temperature annealing. The composite electrodes are characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy and Fourier transform infrared spectroscopy. The content of MnO2 in the MnO2/R-GO@Ni-foam composites is determined by thermal gravimetric analysis. The supercapacitive performance of the composite electroides is investigated by cyclic voltammetry, galvanostatic charge discharge and electrochemical impedance spectroscopy. The results show that the MnO2/R-GO@Ni-foam composite displays a high specific capacitance of 267 F g(-1) at 0.25 A g(-1) and excellent capacitance retention of 89.5% after 1000 cycles. This study provides a facile way for the preparation of composite electrodes for high-performance supercapacitor. (C) 2014 Elsevier B.V. All rights reserved.