Journal of the American Chemical Society, Vol.137, No.7, 2476-2479, 2015
Mechanochemical Ruthenium-Catalyzed Olefin Metathesis
We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis. The method uses commercially available catalysts to achieve high-yielding, rapid, room-temperature metathesis of solid or liquid olefins on a multigram scale using either no or only a catalytic amount of a liquid.