A spirobifluorene-bridged donor/donor chromophore, 2,7-bis-(4-(N,N-diphenylamino)phen-1-yl)-9,9'-spirobifluorene (SPF-TP), was found to combine excellent transparency in the near UV-visible region (lambda(cut-off) <= 420 nm), large two-photon absorption cross-section (4.5 x 10(3)GM) and high thermal stability (T-d = 501 degrees C). In comparison to the reported two-photon absorption molecules, SPF-TP represents the best thermal stability so far described in the literature. The main electronic factors explaining the high two-photon absorption activities of SPF-TP were analyzed by theoretical calculations. Cyclic voltammograms were employed to explore the causes of the excellent transparency of SPF-TP. It was found that the spiroconjugation effect is responsible for the excellent nonlinearity/transparency/thermal stability trade-off in SPF-TP. In addition, SPF-TP is also a good two-photon induced blue fluorescent material with high fluorescence quantum yield (Phi = 0.90, in THF). (C) 2014 Elsevier B.V. All rights reserved.