Solvent extraction of Hf(IV) from acidic chloride solutions has been carried out with PC-88A as an extractant. Increase of acid concentration decreases the percentage extraction of metal indicating the ion exchange type mechanism. The plot of logD vs log[extractant], M is linear with slope 1.8 indicating the association of two moles of extractant with the extracted metal species. Plot of logD vs log[H+] gave a straight line with a negative slope of similar to2 indicating the exchange of two moles of hydrogen ions for every mole of Hf(IV). The effect of Cl- ion concentration at constant concentration of [H+] did not show any change in D values. Addition of sodium salts enhanced the percentage extraction of metal and follows the order NaSCN > NaCl > NaNO3 similar to Na2SO4. Stripping of metal from the loaded organic (LO) with different acids indicated sulphuric acid as the best stripping agent. Regeneration and recycling capacity of PC-88A, temperature, extraction behavior of associated elements was studied. (C) 2004 Elsevier Ltd. All rights reserved.