The dewetting kinetics between a small air-liquid interface and a silica (negatively charged in water) planar surface in solutions of dodecylammonium chloride (cationic surfactant) has been investigated using the Scheludko cell and digital high-speed video microscopy. The gas-liquid interface was created at the bottom of a small silica capillary of the cell and then was moved towards the silica planar surface. After the rupture of the liquid films between the interfaces, the expansion of the gas-liquid-solid three-phase contact (TPC) line was observed and recorded using a digital high-speed video microscope system, operating at 1000 frames/s. The surface tension of the surfactant solution was measured using the pendant drop technique. The equilibrium contact angle was measured using the Scheludko-Minings method with a silica micro-sphere. The TPC radius was determined as a function of time and compared against the available hydrodynamic and molecular-kinetic models. The experimental data are described very well by the molecular-kinetic model for the TPC line motion. The hydrodynamic model is in agreement with the experimental data only for a short time after inception of the three-phase contact expansion. A simplified model was developed for predicting the time of the TPC line expansion in flotation. (C) 2005 Elsevier Ltd. All rights reserved.