화학공학소재연구정보센터
Solid State Ionics, Vol.265, 46-48, 2014
On ion transport mechanism in K+-conducting solid electrolytes based on K3PO4
Data on transport properties of potassium conducting solid electrolytes based on K3PO4 in the systems K-3 - 2xMxPO4 (M = Mg, Ca, Sr, Ba, Zn, Cd, Pb) and K-3 - P-x(1) - xExO4 (E = S, Cr, Mo, W) have been analyzed. The results indicate that, in addition to the usual hopping mechanism, a substantial significance for ion transport in similar phases belongs to the "paddle wheel" mechanism. This mechanism is due to orientation disorder of the PO4 tetrahedra at elevated temperatures, which promotes moving K+ ions to the neighboring vacant positions. (C) 2014 Elsevier B.V. All rights reserved.