The present study introduces an experimental approach to investigate mechanical properties of well-defined non-equilibrium states of Al-Si alloys during cooling from solution annealing. The precipitation behaviour of binary Al-Si alloys during the cooling process has been investigated in a wide cooling rate range (2-0.0001 K/s) with differential scanning calorimetry (DSC). To access the low cooling rate range close to equilibrium an indirect DSC measurement method is introduced. Based on the enthalpy change measured by DSC a physically-based model for the calculation of remaining solute Si amount as function of temperature and cooling rate is presented. Microstructural analyses via light optical microscopy, scanning electron microscopy, atom probe tomography and X-ray diffraction have been performed to evaluate the introduced model and for information on cooling rate dependent precipitate formation. It was found that quench-induced particles of different morphology are formed during cooling. Thermomechanical analyses on clearly distinct undercooled Al-Si states show that flow stress during cooling is dependent on temperature as well as cooling rate. The mechanical behaviour is therefore influenced by solute Si content and quench-induced precipitates. (C) 2015 Elsevier B.V. All rights reserved.