Evaluation of relative permeability coefficients is one of the key steps in reliable simulation of two-phase flow in porous media. An extensive body of work exists on evaluation of these coefficients for two-phase flow under pressure gradient. Oil transport under an applied electrical gradient in porous media is also governed by the principles of two-phase flow, but is less understood. In this paper, relative permeability coefficients under applied electric field are evaluated for a specific case of two- phase fluid flow in water-wet porous media, where the second fluid phase is oil. It is postulated that the viscous drag on the oil phase, exerted by the electro-osmotic flow of the water phase, is responsible for the transport of oil in the absence of a pressure gradient. Reliable prediction of the flow patterns necessitates accurate representation and determination of the relative permeability coefficients under the electrical gradient. The contribution of each phase to the flow is represented mathematically, and the relative permeability coefficients are evaluated through electro-osmotic flow measurements conducted on oil bearing rock cores.