The effect of high-energy milling on the surface properties of quartz is examined with regard to its preg-robbing behavior towards gold. A standard ring mill is used to process dry quartz samples, and the changes in the morphology of the particles, structural deformations and surface chemistry are investigated to explain the increased preg-robbing ability of quartz in acidic chloride solutions. The transition from fine grinding to mechanochemical activation of quartz can be observed from changes in the morphology of the particles, as well as the types of structural deformations. The transition occurs between 1 and 5 min of grinding in the mill used, corresponding to particle sizes around 0.55 mu m. Structural studies differentiate two stages of fine grinding: particle breakage with limited structural disruption, and structural disturbance by mechanochemical alteration, which occurs after particles reach their grinding limits. Quartz keeps its structural order to some degree even after 30 min of aggressive grinding. The surface chemistry of ground quartz demonstrates generation of point defects including low valence silicon and non-bridging oxygen centers. These defect sites play an important role in the surface reactivity of the quartz, and influence the extent of gold loss during preg-robbing. (C) 2013 Elsevier Ltd. All rights reserved.