Korean Journal of Chemical Engineering, Vol.32, No.5, 967-973, May, 2015
Selective sorption behavior of metal(II) ion-imprinted polymethacrylate microspheres synthesized via precipitation polymerization method
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Metal methacrylate complex was synthesized from methacrylic acid and metal carbonate to prepare metal ion-imprinted polymer (MIIP) particles by the precipitation polymerization method. Three types of metal ions, Cu(II), Ni(II), and Pb(II), were used as the template ions in this synthesis. The produced MIIP particles were spherically welldefined with 0.5-2 μm diameter in the order of Cu(II)-MIIP>Ni(II)-MIIP>Pb(II)-MIIP. The imprinted polymers exhibited a much higher adsorption capacity and selectivity toward the target (template) ion than other competitive metal ions. The MIIP particles, Cu(II)-MIIP, Ni(II)-MIIP, and Pb(II)-MIIP, synthesized in this study guaranteed the selective separation of the target metal ion from the mixtures, although their competitive strengths of the adsorption capacity and selectivity were different.
- Shunkevich AA, Martsinkevich RV, Medyak GV, Sokol VP, Filanchuk LP, Soldatov VS, J. Nanosci. Nanotechnol., 77, 249 (2004)
- Gyliene O, Grinciene G, Verbickas R, Butkiene R, Misiunas A, Viteniene I, J. Nanosci. Nanotechnol., 91, 214 (2013)
- Rivas BL, Pooley SA, Maturana HA, Villegas S, Macromol. Chem. Phys., 202, 443 (2001)
- Matis KA, Zouboulis AI, Lazaridis NK, J. Nanosci. Nanotechnol., 3, 143 (2003)
- Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 170(2-3), 969 (2009)
- Martin MI, Lopez FA, Alguacil FJ, Rev. Metal. Madrid., 44, 258 (2008)
- Goyal P, Sharma P, Srivastava S, Srivastava MM, Int. J. Environ. Sci. Technol., 5, 27 (2008)
- Lalhruaitluanga H, Jayaram K, Prasad MNV, Kumar KK, J. Hazard. Mater., 175(1-3), 311 (2010)
- Akhtar M, Iqbal S, Kausar A, Bhanger MI, Shaheen MA, Colloids Surf., B, 75, 149 (2010)
- Hwang ED, Lee KW, Choo KH, Choi SJ, Kim SH, Yoon CH, Lee CH, Desalination, 147(1-3), 289 (2002)
- Bartsch RA, Maeda M, Molecular and ionic recognition with imprinted polymers, American Chemical Society, San Francisco (1997)
- Mosbach K, Ramstrom O, Biol. Biotechnol., 14, 163 (1996)
- Al-Kindy S, Badıa R, Dıaz-Garcıa ME, Anal. Lett., 35, 1763 (2002)
- Al-Kindy S, Badıa R, Suarez-Rodrıguez J, Dıaz-Garcıa ME, Rev. Anal. Chem., 30, 291 (2000)
- Suarez-Rodrıguez JL, Dıaz-Garcıa ME, Anal. Chim. Acta, 405, 67 (2002)
- Kanekiyo Y, Ono Y, Inoue K, Sano M, Shinkai S, J. Chem. Soc. Perkins Trans., 23, 557 (1999)
- Kanekiyo Y, Ono Y, Inoue K, Sano M, Shinkai S, Reinhoudt DN, J. Chem. Soc. Perkin Trans., 12, 2719 (1999)
- Lorenzo CA, Concheiro A, J. Chromatogr., B, 804, 231 (2004)
- Silvestri D, Barbani N, Cristallini C, Giusti P, Ciardelli G, J. Membr. Sci., 282(1-2), 284 (2006)
- Basak G, Das D, Das N, Korean J. Chem. Eng., 31(5), 812 (2014)
- Shi Y, Zhang Q, Feng L, Xiong Q, Chen J, Korean J. Chem. Eng., 31(5), 821 (2014)
- Dam AH, Kim DJ, J. Appl. Polym. Sci., 108(1), 14 (2008)
- Hoai NT, Yoo DK, Kim D, J. Hazard. Mater., 173(1-3), 462 (2010)
- Jiang Y, Kim D, Chem. Eng. J., 166(1), 435 (2011)
- Fan HT, Fan XL, Li J, Guo MM, Zhang DS, Yan F, Sun T, Ind. Eng. Chem. Res., 51(14), 5216 (2012)
- Zhang ML, Zhang ZH, Liu YN, Yang X, Luo LJ, Chen JT, Yao SZ, Chem. Eng. J., 178, 443 (2011)
- Chen JH, Li GP, Liu QL, Ni JC, Wu WB, Lin JM, Chem. Eng. J., 165(2), 465 (2010)
- Fan HT, Liu JX, Yao H, Zhang ZG, Yan F, Li WX, Ind. Eng. Chem. Res., 53(1), 369 (2014)
- Fan HT, Tang Q, Sun Y, Zhang ZG, Li WX, Chem. Eng. J., 258, 146 (2014)
- Behbahani M, Bagheri A, Taghizadeh M, Salarian M, Sadeghi O, Adlnasab L, Jalali K, Food Chem., 138, 2050 (2013)
- Otero-Romani J, Moreda-Pineiro A, Bermejo-Barrera P, Martin-Esteban A, Talanta, 79, 723 (2009)
- Gawin M, Konefał J, Trzewik B, Walas S, Tobiasz A, Mrowiec H, Witek E, Talanta, 80, 1305 (2010)
- Li ZC, Fan HT, Zhang Y, Chen MX, Yu ZY, Cao XQ, Sun T, Chem. Eng. J., 171(2), 703 (2011)
- Hoai NT, Kim D, AIChE J., 52, 3248 (2009)
- Jiang Y, Kim D, Polym. Advan. Technol., 24, 747 (2013)
- Jiang Y, Kim D, J. Nanosci. Nanotechnol., 14, 8578 (2014)