The effect of the divalent metal on the intercalation capacity of stearate anions into layered double hydroxide nanolayers

Mahboobeh Eili; Kamyar Shameli; Nor Azowa Ibrahim; Mansor Bin Ahmad; Wan Md Zin Wan Yunus

Journal of Industrial and Engineering Chemistry, Vol.22, 63-69, February, 2015

DOI10.1016/j.jiec.2014.06.025 Export Citation

The effect of the divalent metal on the intercalation capacity of stearate anions into layered double hydroxide nanolayers

Mahboobeh Eili^†, Kamyar Shameli^{1, †}, Nor Azowa Ibrahim¹, Mansor Bin Ahmad¹, and Wan Md Zin Wan Yunus²

Faculty of Basic Sciences and Advanced Technologies, University of Science and Culture, Avenue, Ashrafi Esfahani Boulevard, Tehran IR14536-33143, Iran, Korea
¹Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang, Selangor 43400, Malaysia
²Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, Kuala Lumpur 57000, Malaysia

E-mail:,

A comparison has been made of the intercalation capacity of the stearate anions into the two different anionic clays: magnesium aluminumlayered double hydroxide (Mg3Al LDH) and zinc aluminum layered double hydroxide (Zn3Al LDH). The anionic clays Mg3Al LDH and Zn3Al LDH were firstly prepared by coprecipitation method from nitrate salts solution and then modified by stearate anions through an ion exchange reaction. The properties, morphologies and ion exchange ability of these two clays have been studied by XRD, TGA, SEM, TEM and CHNS that show the ability of Zn3Al LDH to capture stearate anions is greater than Mg3Al LDH.

Keywords:Layered double hydroxide;Comparison;Intercalation capacity;Elemental analysis;Thermogravimetric analysis

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Eili M, Shameli K, Ibrahim NA, Yunus WMZW, Int. J. Mol. Sci., 13(7), 7938 (2012)
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Cardoso LP, Valim JB, J. Phys. Chem. Solids, 67, 987 (2006)
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[2] Coronado E, Martı-Gastaldo C, Navarro-Moratalla E, Ribera A, Appl. Clay Sci., 48, 228 (2009)

[3] Triantafyllidis KS, Peleka EN, Komvokis VG, Mavros PP, J. Colloid Interface Sci., 342, 427 (2009)

[4] Schwenzer B, Neilson JR, Sivula K, Woo C, Frehet JMJ, Morse DE, Thin Solid Films, 517(19), 5722 (2009)

[5] Delgado RR, Vidaurre MA, De Pauli CP, Ulibarri MA, Avena MJ, J. Colloid Interface Sci., 280(2), 431 (2004)

[6] Da Silva LF, Tronto J, Oliveira HP, Valim JB, J. Incl. Phenom. Macrocycl. Chem., 46, 187 (2003)

[7] Forano C, Hibino T, Leroux F, Taviot-Gueho C, Dev. Clay Sci., 1, 1021 (2006)

[8] Saiah FBD, Su BL, Bettahar N, J. Hazard. Mater., 165(1-3), 206 (2009)

[9] Carrado KA, Kostapapas A, Suib SL, Solid State Ion., 26, 77 (1988)

[10] Prikhod’ko RV, Sychev MV, Astrelin IM, Erdmann K, Mangel A, Van Santen RA, Russ. J. Appl. Chem., 74, 1621 (2001)

[11] Eili M, Shameli K, Ibrahim NA, Yunus WMZW, Int. J. Mol. Sci., 13(7), 7938 (2012)

[12] Hsueh HB, Chen CY, Polymer, 44(4), 1151 (2003)

[13] Cardoso LP, Valim JB, J. Phys. Chem. Solids, 67, 987 (2006)

[14] Mousty C, Kaftan O, Prevot V, Forano C, Sens. Actuators B-Chem., 133, 442 (2008)

[15] Das J, Patra BS, Baliarsingh N, Parida KM, J. Colloid Interface Sci., 316(2), 216 (2007)

[16] Manzi-Nshuti C, Songtipya P, Manias E, Jimenez-Gasco MM, Hossenlopp JM, Wilkie CA, Polymer, 50(15), 3564 (2009)

[17] Thomas GS, Kamath PV, Solid State Sci., 8, 1181 (2006)

[18] Shameli K, Ahmad MB, Jazayeri SD, Shabanzadeh P, Sangpour P, Jahangirian H, Chem. Cent. J., 6(1), 1 (2012)

[19] Pak YL, Ahmad MB, Shameli K, Yunus WMZW, Ibrahim NA, Zainuddin N, J. Nanomater., http://dx.doi.org/10.1155/2013/621097., 1 (2013)

[20] Ahmad MB, Lim JJ, Shameli K, Ibrahim NA, Tay MY, Chieng BW, Chem. Cent. J., 6(1), 1 (2012)

[21] Ahmad MB, Lim JJ, Shameli K, Ibrahim NA, Tay MY, Molecules, 16(9), 7237 (2011)

[22] Pak YL, Ahmad MB, Shameli K, Yunus WMZW, Ibrahim NA, Zainuddin N, Dig. J. Nanomater. Biostruct., 8(4), 1395 (2013)

[23] Liau CP, Ahmad MB, Shameli K, Yunus WMZW, Ibrahim NA, Zainuddin N, Then YY, Sci. World J., 1 (2013)

[24] Basu D, Das A, Stockelhuber KW, Wagenknecht U, Heinrich G, Prog. Polym. Sci, http://dx.doi.org/10.1016/j.progpolymsci.2013.07.011., 1 (2013)

[25] Kameshima Y, Yoshizaki H, Nakajima A, Okada K, J. Colloid Interface Sci., 298(2), 624 (2006)

[26] Liu J, Chen GM, Yang JP, Polymer, 49(18), 3923 (2008)

[27] Xu ZP, Braterman PS, Appl. Clay Sci., 48, 235 (2009)

[28] Hans ML, Lowman AM, Curr. Opin. Solid State Mater. Sci., 6, 319 (2002)

[29] Ortega MJS, Stauner T, Loretz B, Ortega-Vinuesa JL, Bastos-Gonza´ lez D, Wenz G, Schaefer UF, Lehr CM, J. Control. Release, 141, 85 (2010)

[30] Zhang H, Zhang FZ, Ren LL, Evans DG, Duan X, Mater. Chem. Phys., 85(1), 207 (2004)

[31] Pradhan S, Costa FR, Wagenknecht U, Jehnichen D, Bhowmick AK, Heinrich G, Eur. Polym. J., 44, 3122 (2008)

[32] Ding YY, Gui Z, Zhu JX, Hu Y, Wang ZZ, Mater. Res. Bull., 43(12), 3212 (2008)

[33] Costa FR, Leuteritz A, Wagenknecht U, Jehnichen D, Haußler L, Heinrich G, Appl. Clay Sci., 38, 153 (2008)

[34] Ni Z, Xing F, Wang P, Cao G, Appl. Clay Sci., 40, 72 (2008)

[35] Palmer SJ, Frost RL, Nguyen T, Coord. Chem. Rev., 253, 250 (2009)

[36] Cavani F, Trifiro F, Vaccari A, Catal. Today, 11, 173 (1991)

[37] Plank J, Dai Z, Andres PR, Mater. Lett., 60, 3614 (2006)