LiOH-embedded zeolite for carbon dioxide capture under ambient conditions

Youngmin Cho; Ji-Yun Lee; Alok D. Bokare; Soon-Bark Kwon; Duck-Shin Park; Woo-Sung Jung; Jin-Sik Choi; Young-Min Yang; Ju-Yeol Lee; Wonyong Choi

Journal of Industrial and Engineering Chemistry, Vol.22, 350-356, February, 2015

DOI10.1016/j.jiec.2014.07.030 Export Citation

LiOH-embedded zeolite for carbon dioxide capture under ambient conditions

Youngmin Cho^†, Ji-Yun Lee, Alok D. Bokare¹, Soon-Bark Kwon, Duck-Shin Park, Woo-Sung Jung, Jin-Sik Choi, Young-Min Yang, Ju-Yeol Lee², and Wonyong Choi¹

Eco-Rail Research Division, Korea Railroad Research Institute, Uiwang, Republic of Korea
¹School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Republic of Korea
²Technical Institute, Anytech Inc., Suwon, Republic of Korea

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In the present work, commercial zeolites 13X and 5A are embedded with LiOH (LEZ-13X and LEZ-5A) to remove CO2 under simulated indoor conditions. Although the BET surface area of both LEZ sorbents was much smaller than that of bare zeolite material, it showed highly enhanced CO2 adsorption capacity. The requirement of optimummoisture content for maximum CO2 adsorption was established by correlating the relative humidity (RH) values and CO2 uptake. The modified sorbents performed effectively even in presence of air or oxygen carrier gas, which demonstrated its viability to adsorb CO2 from indoor environments at ambient conditions.

Keywords:CO2 adsorption;Lithium hydroxide;Zeolite 5A;Zeolite 13X;Relative humidity

[References]

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Park DU, Ha KC, Environ. Int., 34, 629 (2008)
Kam W, Cheung K, Daher N, Sioutas C, Atmos. Environ., 45, 1506 (2011)
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Chen C, Kim J, Ahn WS, Fuel, 95(1), 360 (2012)
Ridha FN, Manovic V, Macchi A, Anthony EJ, Appl. Energy, 92, 415 (2012)
Won W, Lee S, Lee KS, Sep. Purif. Technol., 85, 120 (2012)
Darde V, van Well WJM, Fosboel PL, Stenby EH, Thomsen K, Int. J. Greenh. Gas Control, 5, 1149 (2011)
Edali M, Idem R, Aboudheir A, Int. J. Greenh. Gas Control, 4, 143 (2010)
Belaissaoui B, Cabot G, Cabot MS, Willson D, Favre E, Energy, 38(1), 167 (2012)
Lau CH, Paul DR, Chung TS, Polymer, 53(2), 454 (2012)
Lee KM, Lim YH, Park CJ, Jo YM, Ind. Eng. Chem. Res., 51(3), 1355 (2012)
Yao Z, Ye Y, Xia M, Environ. Progr. Sustain. Energy, 32, 790 (2013)
Li XS, Xu CG, Chen ZY, Wu HJ, Energy, 36(3), 1394 (2011)
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Walton KS, Abney MB, LeVan MD, Microporous Mesoporous Mater., 91, 78 (2006)
Yang ST, Kim J, Ahn WS, Microporous Mesoporous Mater., 135, 90 (2010)
Bulanek R, Frolich K, Frydova E, Cicmanec P, Top. Catal., 53, 1349 (2010)
Li G, Xiao P, Webley P, Zhang J, Singh R, Marshall M, Adsorption, 14, 415 (2008)
Lee KM, Jo YM, J. Korean Soc. Atmos. Environ., 25, 316 (2009)
Cho Y, Lee JY, Kwon SB, Park DS, Lee JY, J. Korean Soc. Atmos. Environ., 27, 191 (2011)
Merel J, Clausse M, Meunier F, Environ. Prog., 25, 327 (2006)
Wang Y, Levan MD, J. Chem. Eng. Data, 54(10), 2839 (2009)
Zhao Z, Cui X, Ma J, Li R, Int. J. Greenh. Gas Control, 1, 355 (2007)
Choi S, Drese JH, Eisenberger PM, Jones CW, Environ. Sci. Technol., 45, 2420 (2011)
Choi S, Gray ML, Jones CW, ChemSusChem, 4, 628 (2011)
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Chaikittisilp W, Kim HJ, Jones CW, Energy Fuels, 25(11), 5528 (2011)
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[3] Park DU, Ha KC, Environ. Int., 34, 629 (2008)

[4] Kam W, Cheung K, Daher N, Sioutas C, Atmos. Environ., 45, 1506 (2011)

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[10] Edali M, Idem R, Aboudheir A, Int. J. Greenh. Gas Control, 4, 143 (2010)

[11] Belaissaoui B, Cabot G, Cabot MS, Willson D, Favre E, Energy, 38(1), 167 (2012)

[12] Lau CH, Paul DR, Chung TS, Polymer, 53(2), 454 (2012)

[13] Lee KM, Lim YH, Park CJ, Jo YM, Ind. Eng. Chem. Res., 51(3), 1355 (2012)

[14] Yao Z, Ye Y, Xia M, Environ. Progr. Sustain. Energy, 32, 790 (2013)

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[16] Wang X, Ma X, Schwartz V, Clark JC, Overbury SH, Zhao S, Xu X, Song C, Phys. Chem. Chem. Phys., 14, 1485 (2012)

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[18] Chen C, Ahn WS, Chem. Eng. J., 166(2), 646 (2011)

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[20] Saha D, Bao Z, Jia F, Deng S, Environ. Sci. Technol., 44, 1820 (2010)

[21] Zukal A, Pawlesa J, Cejka J, Adsorption, 15, 264 (2009)

[22] Zukal A, Arean CO, Delgado MR, Nachtigall P, Pulido A, Mayerova J, Microporous Mesoporous Mater., 146, 97 (2011)

[23] Satyapal S, Filburn T, Trela J, Strange J, Energy Fuels, 15(2), 250 (2001)

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