화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.23, 21-26, March, 2015
DOI10.1016/j.jiec.2014.08.033  Export Citation
Novel MoP/HY catalyst for the selective conversion of naphthalene to tetralin
Muhammad Usman, Dan Li, Rauf Razzaq, Muhammad Yaseen, Chunshan Li†, and Suojiang Zhang†
  • Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, PR China
E-mail:,
MoP catalyst supported on HZSM-5, HBeta and HY were prepared by wet impregnation and temperature programmed reduction (H2-TPR), applied for the conversion of naphthalene to tetralin, and characterized by XRD, SEM, TEM, BET, H2-TPR, and NH3-TPD. Catalytic tests revealed the highest selectivity to tetralin was observed over MoP/HY with a naphthalene conversion of 85% and a tetralin selectivity of 99%. The effect of temperature and liquid hourly space velocity (LHSV) was also studied. Well dispersed and small particles of MoP, reduced pore size and weak acidity of HY contribute to enhanced catalytic activity and selectivity in conversion of naphthalene to tetralin.
Keywords:Coal tar;Naphthalene;MoP;Hydrogenation;Zeolite
  1. Li C, Suzuki K, Resour. Conserv. Recycl., 54, 905 (2010)
  2. Blum P, Sagner A, Tiehm A, Martus P, Wendel T, Grathwohl P, J. Contam. Hydrol., 126, 181 (2011)
  3. Li C, Suzuki K, Renew. Sust. Energ. Rev., 13, 594 (2009)
  4. Kan T, Sun XY, Wang HY, Li CS, Muhammad U, Energy Fuels, 26(6), 3604 (2012)
  5. Nishijima A, Kameoka T, Sato T, Matsubayashi N, Nishimura Y, Catal. Today, 45(1-4), 261 (1998)
  6. Li CS, Hirabayashi D, Suzuki K, Bioresour. Technol., 101, S97 (2010)
  7. Lin SD, Song CS, Catal. Today, 31(1-2), 93 (1996)
  8. Lu CM, Lin YM, Wang I, Appl. Catal. A: Gen., 198(1-2), 223 (2000)
  9. Jacquin M, Jones DJ, Roziere J, Albertazzi S, Vaccari A, Lenarda M, Storaro L, Ganzerla R, Appl. Catal. A: Gen., 251(1), 131 (2003)
  10. Albertazzi S, Busca G, Finocchio E, Glockler R, Vaccari A, J. Catal., 223(2), 372 (2004)
  11. Monteiro-Gezork ACA, Natividad R, Winterbottom JM, Catal. Today, 130(2-4), 471 (2008)
  12. Chen HL, Yang H, Omotoso O, Ding LH, Briker Y, Zheng Y, Ring Z, Appl. Catal. A: Gen., 358(2), 103 (2009)
  13. Grzechowiak JR, Masalska A, Jaroszewska K, Sadowska K, Catal. Today, 176(1), 149 (2011)
  14. Chen S, Chen J, Gieleciak R, Fairbridge C, Appl. Catal. A: Gen., 415-416, 70 (2012)
  15. Mandreoli M, Vaccari A, Veggetti E, Jacquin M, Jones DJ, Roziere J, Appl. Catal. A: Gen., 231(1-2), 263 (2002)
  16. Romero CMC, Thybaut JW, Marin GB, Catal. Today, 130(1), 231 (2008)
  17. Li CS, Wang MR, Dai F, Wang HY, Suzuki K, Zhang SJ, Renew. Sust. Energ. Rev., 5, 3106 (2013)
  18. Liu X, Ardakani SJ, Smith KJ, Catal. Commun., 12, 454 (2011)
  19. Li CS, Hirabayashi D, Suzuki K, Mater. Res. Bull., 46(8), 1307 (2011)
  20. Shirai M, Rode CV, Mine E, Sasaki A, Sato O, Hiyoshi N, Catal. Today, 115(1-4), 248 (2006)
  21. Zhao HY, Li D, Bui P, Oyama ST, Appl. Catal. A: Gen., 391(1-2), 305 (2011)
  22. Shu YY, Lee YK, Oyama ST, J. Catal., 236(1), 112 (2005)
  23. Kawai T, Bando KK, Lee YK, Oyama ST, Chun WJ, Asakura K, J. Catal., 241(1), 20 (2006)
  24. Phillips DC, Sawhill SJ, Self R, Bussell ME, J. Catal., 207(2), 266 (2002)
  25. Whiffen VML, Smith KJ, Straus SK, Appl. Catal. A: Gen., 419-420, 111 (2012)
  26. Zuzaniuk V, Prins R, J. Catal., 219(1), 85 (2003)
  27. Sawhill SJ, Layman KA, Van Wyk DR, Engelhard MH, Wang C, Bussell ME, J. Catal., 231(2), 300 (2005)
  28. Li D, Bui P, Zhao HY, Oyama ST, Dou T, Shen ZH, J. Catal., 290, 1 (2012)
  29. Oyama ST, Wang X, Lee YK, Bando K, Requejo FG, J. Catal., 210(1), 207 (2002)
  30. Stinner C, Prins R, Weber T, J. Catal., 191(2), 438 (2000)
  31. Bhatia S, Abdullah AZ, Wong CT, J. Hazard. Mater., 163(1), 73 (2009)
  32. JCPDS Powder Diffraction File, International Centre for Diffraction Data, Swarthmore, PA, 2000.
  33. Kim YS, Yun GN, Lee YK, Catal. Commun., 45, 133 (2014)
  34. Thomas R, Moulijn JA, Beer VHJD, Medema J, J. Mol. Catal. A-Chem., 8, 161 (1980)
  35. Oyama ST, Wang X, Lee YK, Chun WJ, J. Catal., 221(2), 263 (2004)
  36. Berteau P, Delmon B, Catal. Today, 5, 121 (1989)
  37. Soni KK, Boahene PE, Rambabu N, Dalai AK, Adjaye J, Catal. Today, 207, 119 (2013)
  38. Bunch AY, Ozkan US, J. Catal., 206(2), 177 (2002)
  39. Liu C, Liu Y, Li W, Cui M, Liu C, Pet. Sci. Technol., 24, 207 (2006)
  40. Lin SD, Vannice MA, J. Catal., 143, 563 (1993)
  41. Bando KK, Soga K, Kunimori K, Arakawa H, Appl. Catal. A: Gen., 175(1-2), 67 (1998)
  42. Wang J, Chen HY, Li QZ, React. Kinet. Catal. Lett., 69(2), 277 (2000)
  43. Zhang X, Zhang Q, Guan J, He D, Hu H, Liang C, Asia-Pac. J. Chem. Eng., 4, 574 (2009)