화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.23, 57-66, March, 2015
Assessment of corrosion inhibitive behavior of 2-aminothiophenol derivatives on carbon steel in 1 M HCl
E-mail:
The inhibition effect of three newly synthesized 2-aminothiophenol derivatives on the corrosion of carbon steel in 1 M HCl was investigated using electrochemical measurements and quantum chemical calculations. The experimental results suggest that these compounds are efficient corrosion inhibitors and the inhibition efficiencies increase with increasing their concentrations. The efficiencies obtained from EIS measurements were in good agreement with those obtained from the polarization measurements. Polarization measurements show that these inhibitors act as mixed-type inhibitors. The adsorption of these inhibitors was found to obey Langmuir adsorption model. The computed quantum chemical properties show good correlation with experimental inhibition efficiencies.
  1. Fouda AS, Mostafa HA, Heakal FE, Elewady GY, Corrosion Sci., 47, 1988 (2005)
  2. Abdallah M, Helal EA, Fouda AS, Corrosion Sci., 48, 1639 (2006)
  3. Zhang ST, Tao ZH, Li WH, Hou BR, Appl. Surf. Sci., 255(15), 6757 (2009)
  4. Nathan CC, Organic Inhibitors, NACE, Houston, TX, 1977.
  5. Hosseini SMA, Azimi A, Corrosion Sci., 51, 728 (2009)
  6. Ali SA, Saeed MT, Rahman SU, Corrosion Sci., 45, 253 (2003)
  7. Pardave M, Romero M, Hernandez H, Quijano M, Likhanova N, Uruchurtu J, Garcia J, Corrosion Sci., 54, 231 (2012)
  8. Ismayilov IT, El-Lateef HMA, Abbasov VM, Aliyeva LI, Efremenko EN, Qasimov EE, Mamedxanova SA, Adv. Mater. Corros., 1, 22 (2012)
  9. Abbasov VM, El-Lateef HMA, Aliyeva LI, Ismayilov IT, Qasimov EE, J. Korean Chem. Soc., 57, 25 (2013)
  10. Chetouani A, Hammouti B, Benhadda T, Daoudi M, Appl. Surf. Sci., 249(1-4), 375 (2005)
  11. Herrag L, Hammouti B, Elkadiri S, Aouniti A, Jama C, Vezin H, Bentiss F, Corrosion Sci., 52, 3042 (2010)
  12. Raicheva SN, Aleksiev BV, Sokolova EI, Corrosion Sci., 34, 343 (1993)
  13. Ahamad I, Prasad R, Quraishi MA, Mater. Chem. Phys., 124(2-3), 1155 (2010)
  14. Musa AY, Jalgham RTT, Mohamad AB, Corrosion Sci., 56, 176 (2012)
  15. Rutkauskas K, Beresnevicius ZI, Chem. Heterocycl. Compd., 42(2), 227 (2006)
  16. Hamaide T, Zicmanis A, Monnet C, Guyot A, Polym. Bull., 33(2), 133 (1994)
  17. Al-Sabagh AM, Atta AM, J. Chem. Technol. Biotechnol., 74(11), 1075 (1999)
  18. Tang Y, Zhang F, Hu S, Cao Z, Wu Z, Jing W, Corrosion Sci., 74, 271 (2013)
  19. Issaadi S, Douadi T, Zouaoui A, Chafaa S, Khan MA, Bouet G, Corrosion Sci., 53, 1484 (2011)
  20. Jacob KS, Parameswaran G, Corrosion Sci., 52, 224 (2010)
  21. Negm NA, Kandile NG, Badr EA, Mohammed MA, Corrosion Sci., 65, 94 (2012)
  22. da Rocha JC, Gomes JACP, D’Elia E, Corrosion Sci., 52, 2341 (2010)
  23. Zhang F, Tang Y, Cao Z, Jing W, Wu Z, Chen Y, Corrosion Sci., 61, 1 (2012)
  24. Mahadavian M, Attar MM, Corrosion Sci., 48, 4152 (2006)
  25. Popova A, Sokolova E, Raicheva S, Christov M, Corrosion Sci., 45, 33 (2003)
  26. Abdel-Gaber AM, Masoud MS, Khalil EA, Shehata EE, Corrosion Sci., 51, 3021 (2009)
  27. Moradi M, Duan J, Du X, Corrosion Sci., 69, 338 (2013)
  28. Istiaque A, Rajendra P, Quraisi MA, Corrosion Sci., 52(4), 1472 (2010)
  29. Bentiss F, Mehdi B, Mernari B, Traisnel M, Vezin H, Corrosion, 58(5), 399 (2002)
  30. Qian B, Wang J, Zheng M, Hou B, Corrosion Sci., 75, 184 (2013)
  31. Negm NA, Badr EA, Aiad IA, Zaki MF, Said MM, Corrosion Sci., 65, 77 (2012)
  32. Behpour M, Ghoreishi SM, Soltani N, Salavati-Niasari M, Hamadanian M, Gandomi A, Corrosion Sci., 50, 2172 (2008)
  33. Aljourani J, Raeissi K, Golozar MA, Corrosion Sci., 51, 1836 (2009)
  34. Azhar ME, Mernari B, Traisnel M, Bentiss F, Lagrenee M, Corrosion Sci., 43, 2229 (2001)
  35. Badawy WA, Ismail KM, Fathi AM, Electrochim. Acta, 51(20), 4182 (2006)
  36. Yurt A, Bereket G, Kivrak A, Balaban A, Erk B, J. Appl. Electrochem., 35(10), 1025 (2005)
  37. Solmaz R, Kardas G, Culha M, Yazici B, Erbil M, Electrochim. Acta, 53(20), 5941 (2008)
  38. Hassan N, Holze R, J. Chem. Sci., 121, 693 (2009)
  39. Ma H, Chen S, Liu Z, Sun Y, J. Mol. Struct., 774, 19 (2006)
  40. Yadav DK, Maiti B, Quraishi MA, Corrosion Sci., 52, 3586 (2010)
  41. Fu JJ, Zang HS, Wang Y, Li SN, Chen T, Liu XD, Ind. Eng. Chem. Res., 51(18), 6377 (2012)
  42. Gece G, Corrosion Sci., 50, 2981 (2008)
  43. Obot IB, Obi-Egbedi NO, Corrosion Sci., 53, 263 (2011)
  44. Zhao P, Liang Q, Li Y, Appl. Surf. Sci., 252(5), 1596 (2005)
  45. Khalil N, Electrochim. Acta, 48(18), 2635 (2003)
  46. Fleming I, Frontier Orbitals and Organic Chemical Reactions, John Wiley and Sons, New York, 1976.
  47. Khaled KF, Mater. Chem. Phys., 112(1), 104 (2008)
  48. Khaled KF, Electrochim. Acta, 53(9), 3484 (2008)
  49. Hansch C, Leo A, Substituent for Correlation Analysis in Chemistry and Biology, Wiley, New York, NY, USA, 1979.
  50. Eddy NO, Ebenso EE, J. Mol. Model., 16, 1291 (2010)
  51. Eddy NO, Ibok UJ, Ebenso EE, Nemr AE, Ashry HEE, J. Mol. Model., 15, 1085 (2009)
  52. Arslan T, Kandemirli F, Ebenso EE, Love I, Alemu H, Corrosion Sci., 51, 35 (2009)