Micelle mediated extraction for preconcentration of Eu(III) prior to determination by flame atomic absorption spectrometry

El Said A. Nouh

Journal of Industrial and Engineering Chemistry, Vol.24, 87-91, April, 2015

DOI10.1016/j.jiec.2014.09.013 Export Citation

Micelle mediated extraction for preconcentration of Eu(III) prior to determination by flame atomic absorption spectrometry

El Said A. Nouh^†

Nuclear Materials Authority, P.O. Box 530, El Maadi, Cairo, Egypt

E-mail:

Cloud point extraction (CPE) was used for Eu(III) determination in water samples using flame atomic absorption spectrometry (FAAS). Complex of Eu(III) with alizarin red S was extracted into the surfactant-rich phase of octylphenoxypolyethoxyethanol (Triton X-114) from samples at room temperature in presence of an amount of NaNO3. The parameters affecting CPE such as sample pH and concentrations of NaNO3, complexing agent and Triton X-114 were studied. Under the optimized conditions, the limit of detection (3σ) was 6 ng mL?1 and the relative standard deviation (RSD) was 1.95%. The method was successfully applied to Eu(III) determination in water samples.

Keywords:Cloud point extraction;Europium;Atomic absorption spectrometry

[References]

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[2] Xu GX, Rare Earth, Metallurgy Industry Press, Beijing, 1996.

[3] Heller A, Barkleit A, Bernhard G, Chem. Res. Toxicol., 24, 193 (2011)

[4] Ohnishi K, Usuda K, Nakayama S, Sugiura Y, Kitamura Y, Kurita A, Tsuda Y, Kimura M, Kono K, Biol. Trace Elem. Res., 143, 1054 (2011)

[5] Ni JZ, Bio-Inorganic Chemistry of Rare Earth, Science Press, Beijing, 1995.

[6] Sabbioni E, Pietra R, Gaglione P, Vocaturo G, Colombo G, Sci. Total Environ., 26, 19 (1982)

[7] Koeberl C, Bayer PJ, J. Alloy. Compd., 180, 63 (1992)

[8] Zamani HA, Imani A, Arvinfar A, Rahimi F, Ganjali MR, Faridbod F, Meghdadi S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 588 (2011)

[9] Fujimori F, Hayashi T, Inagaki K, Haraguchi H, Fresenius J. Anal. Chem., 363, 277 (1999)

[10] Shabani MB, Akagi T, Shimizu H, Masuda A, Anal. Chem., 62, 2709 (1990)

[11] Zhang TH, Shan XQ, Liu RX, Tang HX, Zhang SZ, Anal. Chem., 70, 3964 (1998)

[12] Liang P, Hu B, Jiang ZC, Qin YC, Peng TY, J. Anal. At. Spectrom., 16, 863 (2001)

[13] Vicente Q, Padro A, Martinez L, Olsina R, Spectroc. Acta Pt. B-Atom. Spectr., 53, 1281 (1998)

[14] Moller P, Dulski P, Luck J, Spectroc. Acta Pt. B-Atom. Spectr., 47, 1379 (1992)

[15] Shuai Q, Hu B, Qin YC, Wanjau R, Jiang ZC, J. Anal. At. Spectrom., 15, 1413 (2000)

[16] Watanabe H, Saitoh T, Kamidate T, Haraguchi K, Mikrochim. Acta, 106, 83 (1992)

[17] El-Naggar WS, Lasheen TA, Nouh EA, Ghonaim AK, Cent. Eur. J. Chem., 8, 34 (2010)

[18] Tang AN, Jiang DQ, Yan XP, Anal. Chim. Acta, 507, 199 (2004)

[19] Silva MF, Fernandez L, Olsina RA, Stacchiola D, Anal. Chim. Acta, 342, 229 (1997)

[20] Ohashi A, Tsuguchi A, Imura H, Ohashi K, Anal. Sci., 20, 1091 (2004)

[21] Ohashi A, Ito H, Kanai C, Imura H, Ohashi K, Talanta, 65, 525 (2005)

[22] Tang AN, Ding GS, Yan XP, Talanta, 67, 942 (2005)

[23] Surme Y, Narin I, Soylak M, Yuruk H, Dogan M, Mikrochim. Acta, 157, 193 (2007)

[24] Ghaedi M, Shokrollahia A, Niknamb K, Niknama E, Soylak M, Cent. Eur. J. Chem., 7, 148 (2009)

[25] Candira S, Narinb I, Soylakc M, Talanta, 77, 289 (2008)

[26] de Wuilloud JCA, Wuilloud RG, Silva MF, Olsina RA, Martinez LD, Spectroc. Acta Pt. B-Atom. Spectr., 57B, 365 (2002)

[27] Miuar J, Ishii H, Watanabe H, Jpn. Soc. Anal. Chem., 25, 808 (1976)

[28] Afkhami A, Madrakian T, Siampour H, J. Hazard. Mater., 138(2), 269 (2006)

[29] da Silva MAM, Frescura VLA, Aguilera FJN, Curtius AJ, J. Anal. At. Spectrom., 13, 1369 (1998)

[30] Paleologos EK, Koupparis MA, Karayannis MI, Veltsistas PG, Anal. Chem., 73, 4428 (2001)

[31] Bellato ACS, Gervasio APG, Gine MF, J. Anal. At. Spectrom., 20, 535 (2005)

[32] Manzoori JL, Tabrizi AB, Microchem. J., 72, 1 (2002)

[33] Hung KC, Chen BH, Yu LE, Sep. Purif. Technol., 57(1), 1 (2007)

[34] Schott H, Royce AE, J. Pharm. Sci., 73, 793 (1984)

[35] Horvath WJ, Huie CW, Talanta, 39, 487 (1992)

[36] Shikata T, Okuzono M, Sugimoto N, Macromolecules, 46(5), 1956 (2013)

[37] Dilip M, Griffin ST, Spear SK, Rodriguez H, Rijksen C, Rogers RD, Ind. Eng. Chem. Res., 49(5), 2371 (2010)

[38] Ortega C, Cerutti S, Olsina RA, Silva MF, Martinez LD, Anal. Bioanal. Chem., 375, 270 (2003)

[39] Favre-Reguillon A, Draye M, Lebuzit G, Thomas S, Foos J, Cote G, Guy A, Talanta, 63, 803 (2004)

[40] Mustafina A, Elistratova J, Burilov A, Knyazeva I, Zairov R, Amirov R, Solovieva S, Konovalov A, Talanta, 68, 863 (2006)

[41] Ohashi A, Hashimoto T, Imura H, Ohashi K, Talanta, 73, 893 (2007)

[42] Mortada WI, Ali AZ, Hassanien MM, Anal. Methods, 5, 5234 (2013)

[43] Laepsada MEF, Pavon JLP, Cardero BM, Analyst, 118, 209 (1993)

[44] Frankewich RP, Hinze WL, Anal. Chem., 66, 944 (1994)

[45] Cai B, Hu B, Xiong H, Liao Z, Mao L, Jiang Z, Talanta, 55, 85 (2001)

[46] Chen S, Zhao H, Wang X, Li X, Jin L, Anal. Chim. Acta, 506, 25 (2004)

[47] Maind SD, Chattopadhyay N, Gandhi C, Kumar SC, Sudersanan M, Sci. Justice, 48, 61 (2008)

[48] Clerc SD, Jewsbury RA, Mortimer MG, Zeng J, Anal. Chim. Acta, 339, 225 (1997)

[49] Liawruangrath S, Sakulkhaemaruethai S, Talanta, 59, 9 (2003)