New PLA/PEI-functionalized Fe3O4 nanocomposite: Preparation and characterization

Meisam Shabanian; Mehdi Khoobi; Farideh Hemati; Hossein Ali Khonakdar; Seyed esmaeil Sadat ebrahimi; Udo Wagenknecht; Abbas Shafiee

Journal of Industrial and Engineering Chemistry, Vol.24, 211-218, April, 2015

DOI10.1016/j.jiec.2014.09.032 Export Citation

New PLA/PEI-functionalized Fe3O4 nanocomposite: Preparation and characterization

Meisam Shabanian, Mehdi Khoobi¹, Farideh Hemati, Hossein Ali Khonakdar², Seyed esmaeil Sadat ebrahimi¹, Udo Wagenknecht³, and Abbas Shafiee^{1, †}

Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute (SRI), P.O. Box 31745-139, Karaj, Iran
¹Department of Medicinal Chemistry, Faculty of Pharmacy and Pharmaceutical Sciences Research Center, Tehran University of Medical Sciences, Tehran 14176, Iran
²Department of Polymer Engineering, Faculty of Engineering, South Tehran Branch, Islamic Azad University, Tehran, P.O.Box: 19585-466, Iran
³Leibniz-Institute of Polymer Research, D-01069 Dresden, Germany

E-mail:

In this work, Fe3O4 nanoparticles were functionalized with hyperbranched polyethylenimine (PEI). The neat Fe3O4 nanoparticles (MNP) and functionalized Fe3O4 (MNP@PEI) were separately incorporated into a polylactic acid (PLA). Compared to the neat MNP, the functionalized nanoparticles (MNP@PEI) had better dispersion in the PLA matrix. The properties of the nanocomposites were strongly related to the dispersion and interaction between the nanoparticles and PLA matrix. The heat barrier effect and high nitrogen content of the MNP@PEI nanoparticles were found to be responsible for the improvement of the thermal and flame resistance properties.

Keywords:Nanocomposite;Magnetic nanoparticles;Functional nanoparticles;Polylactic acid

[References]

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Gholamian F, Shabanian M, Shahrokh M, J. Clust. Sci., 24, 177 (2013)
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Lu R, Xu B, Tao K, Dou H, Qiu Y, Sun K, Zhang Y, Wu L, Sun K, Colloid Polym. Sci., 290, 63 (2012)
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[Referenced By]

[1] Cornell RM, Schwertmann U, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses, Wiley, Weinheim, 2006.

[2] Mehdinia A, Roohi F, Jabbari A, J. Chromatogr. A, 1218, 4269 (2011)

[3] Liang RP, Yao GH, Fan LX, Qiu JD, Anal. Chim. Acta, 737, 22 (2012)

[4] Panneerselvam P, Morad N, Tan KA, J. Hazard. Mater., 186(1), 160 (2011)

[5] Choo KH, Kang SK, Desalination, 154(2), 139 (2003)

[6] Mu B, Liu P, Dong Y, Lu CY, Wu XL, J. Polym. Sci. A: Polym. Chem., 48(14), 3135 (2010)

[7] Nabiyouni G, Ghanbari D, J. Appl. Polym. Sci., 125(1), 3268 (2012)

[8] Dormann JL, Fiorani D, Magnetic properties of fine particles, in: Proceedings of the International Workshop on Studies of Magnetic Properties of Fine Particles and their Relevance to Materials Science, Rome, Italy, November 4.8, 1991, North-Holland, 1992.

[9] Gholamian F, Shabanian M, Shahrokh M, J. Clust. Sci., 24, 177 (2013)

[10] Ghosh S, Puri IK, Soft Matter, 9, 2024 (2013)

[11] Lu R, Xu B, Tao K, Dou H, Qiu Y, Sun K, Zhang Y, Wu L, Sun K, Colloid Polym. Sci., 290, 63 (2012)

[12] Millan A, Palacio F, Falqui A, Snoeck E, Serin V, Bhattacharjee A, Ksenofontov V, Gutlich P, Gilbert I, Acta Mater., 55, 2201 (2007)

[13] Ballav N, Choi HJ, Mishra SB, Maity A, J. Ind. Eng. Chem., 20(6), 4085 (2014)

[14] Ghanbari D, Salavati-Niasari M, Ghasemi-Kooch M, J. Ind. Eng. Chem., 20(6), 3970 (2014)

[15] Nabiyouni G, Julaee M, Ghanbari D, Aliabadi PC, Safaie N, J. Ind. Eng. Chem. (2014)

[16] Sayar O, Torbati NA, Saravani H, Mehrani K, Behbahani A, Zadeh HRM, J. Ind. Eng. Chem., 20(5), 2657 (2014)

[17] De La Cruz-Montoya E, Rinaldi C, J. Appl. Phys., 107, 09B506 (2010)

[18] Xulu PM, Filipcsei G, Zrinyi M, Macromolecules, 33(5), 1716 (2000)

[19] Gomez-Lopera SA, Arias JL, Gallardo V, Delgado AV, Langmuir, 22(6), 2816 (2006)

[20] Xu CH, Ouyang CF, Jia RP, Li YS, Wang X, J. Appl. Polym. Sci., 111(4), 1763 (2009)

[21] Kango S, Kalia S, Celli A, Njuguna J, Habibi Y, Kumar R, Prog. Polym. Sci., 38, 1232 (2013)

[22] Skaff H, Emrick T, Angew. Chem.-Int. Edit., 43, 5383 (2004)

[23] Jeon IY, Baek JB, Materials, 3, 3654 (2010)

[24] Peng Q, Lai DMY, Kang ET, Neoh KG, Macromolecules, 39(16), 5577 (2006)

[25] Taniguchi Y, Ogawa M, Gang W, Saitoh H, Fujiki K, Yamauchi T, Tsubokawa N, Mater. Chem. Phys., 108(2-3), 397 (2008)

[26] Mirzajani R, Ahmadi S, J. Ind. Eng. Chem. (2014)

[27] Shabanian M, Khoobi M, Hemati F, Khonakdar HA, Faghihi K, Wagenknecht U, Ebrahimi SES, Shafiee A, Particuology. 2014

[28] Solarski S, Ferreira M, Devaux E, Polymer, 46(25), 11187 (2005)

[29] Shabanian M, Kang NJ, Wang DY, Wagenknecht U, Heinrich G, Polym. Degrad. Stabil., 98, 1036 (2013)

[30] Sinclair RG, J. Macromol. Sci. Part A, 33, 585 (1996)

[31] Auras RA, Lim LT, Selke SEM, Tsuji H, Poly(lactic acid): Synthesis, Structures, Properties, Processing, and Applications, Wiley, New Yourk, 2010.

[32] Bang G, Kim SW, J. Ind. Eng. Chem., 18(3), 1063 (2012)

[33] Fukushima K, Murariu M, Camino G, Dubois P, Polym. Degrad. Stabil., 95, 1063 (2010)

[34] Ray SS, Yamada K, Okamoto M, Ueda K, Nano Lett., 2, 1093 (2002)

[35] Wang DY, Gohs U, Kang NJ, Leuteritz A, Boldt R, Wagenknecht U, Heinrich G, Langmuir, 28(34), 12601 (2012)

[36] Li HY, Chang CM, Hsu KY, Liu YL, J. Mater. Chem., 22, 4855 (2012)

[37] Svagan AJ, Akesson A, Cardenas M, Bulut S, Knudsen JC, Risbo J, Plackett D, Biomacromolecules, 13(2), 397 (2012)

[38] Murariu M, Doumbia A, Bonnaud L, Dechief AL, Paint Y, Ferreira M, Campagne C, Devaux E, Dubois P, Biomacromolecules, 12(5), 1762 (2011)

[39] Zois D, Vartzouma C, Deligiannakis Y, Hadjiliadis N, Casella L, Monzani E, Louloudi M, J. Mol. Catal. A-Chem., 261(2), 306 (2007)

[40] Ho J, Al-Deen FMN, Al-Abboodi A, Selomulya C, Xiang SD, Plebanski M, Forde GM, Colloids Surf. B: Biointerfaces, 83, 83 (2011)

[41] Gubin SP, Magnetic Nanoparticles, Wiley, 2009.

[42] Varadan VK, Chen LF, Xie J, Nanomedicine: Design and Applications of Magnetic Nanomaterials, Nanosensors and Nanosystems, Wiley, 2008.