Cu0.5Mn0.5Fe2O4 nano spinels as potential sorbent for adsorption of brilliant green

Saeedeh Hashemian; Atena Dehghanpor; Mahnaz Moghahed

Journal of Industrial and Engineering Chemistry, Vol.24, 308-314, April, 2015

DOI10.1016/j.jiec.2014.10.001 Export Citation

Cu0.5Mn0.5Fe2O4 nano spinels as potential sorbent for adsorption of brilliant green

Saeedeh Hashemian^†, Atena Dehghanpor, and Mahnaz Moghahed

Yazd Branch, Yazd Branch, Islamic Azad University, Yazd, Iran

E-mail:

Nano spinels of CuxMn1-xFe2O4 (x = 0.0, 0.2, 0.4, 0.5, 0.8 and 1) have been synthesized. Nano-particles of CuxMn1?xFe2O4 were characterized by FTIR, XRD and SEM. The adsorption of brilliant green (BG) by nano particles of CuxMn1?xFe2O4 was studied. Results showed that adsorption activity of nano particles are as followed: MnFe2O4 < CuFe2O4 < Mn0.2Cu0.8Fe2O4 < Mn0.8Cu0.2Fe2O4 < Mn0.4Cu0.6Fe2O4 < Mn0.5Cu0.5Fe2O4. The adsorption of BG followed pseudo-second-order kinetic model. Thermodynamic results revealed that the adsorption of BG onto Mn0.5Cu0.5Fe2O4 particles is endothermic and spontaneously process. The adsorption equilibrium was best described by the Langmuir model. The nano particles of Mn0.5Cu0.5Fe2O4 can be conveniently regenerated by chemical and physical methods after adsorption.

Keywords:Adsorption;Nano spinel;CuxMn1-xFe2O4;Brilliant green

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[Referenced By]

[1] Mai FD, Chen CC, Chen JL, Liu SC, J. Chromatogr. A, 1189(1-2), 355 (2008)

[2] Gupta VK, Suhas, J. Environ. Eng.-ASCE, 90(8), 2313 (2009)

[3] Hashemian S, Salari K, Yazdi ZA, J. Ind. Eng. Chem., 20(4), 1892 (2014)

[4] Hashemian S, Sadeghi B, Mangeli M, J. Ind. Eng. Chem. (2014)

[5] Crini G, Bioresour. Technol., 97(9), 1061 (2006)

[6] Hashemian S, Monshizadeh M, Main Group Chem., 12, 113 (2013)

[7] Hashemian S, Afr. J. Biotechnol., 9(50), 8667 (2010)

[8] Hashemian S, Main Group Chem., 10, 105 (2011)

[9] Liu HN, Qing BJ, Ye XS, Li Q, Lee KT, Wu ZJ, Chem. Eng. J., 151(1-3), 235 (2009)

[10] Sivarajasekar N, Baskar R, J. Ind. Eng. Chem., 20(5), 2699 (2014)

[11] Amici J, Celasco E, Allia P, Tiberto P, Sangermano M, Macromol. Chem. Phys., 212, 411 (2011)

[12] Koseoglu Y, Bay M, Tan M, Baykal A, Sozeri H, Topkaya R, Akdogan N, J. Nanopart. Res., 13, 2235 (2011)

[13] Abareshi M, Goharshadi EK, Zebarjad SM, Fadafan HK, Youssefi A, J. Magn. Mater., 322, 3895 (2010)

[14] Gozuak F, Koseoglu Y, Baykal A, Kavas H, J. Magn. Magn. Mater., 322, 2170 (2009)

[15] Kavas H, Baykal A, Toprak MS, Koseoglu Y, Sertkol M, Aktas B, J. Alloy. Compd., 479, 49 (2009)

[16] Han M, Ou Y, Chen W, Deng L, J. Alloy. Compd., 474, 185 (2009)

[17] Giri J, Sriharsha T, Asthana S, Rao TKG, Nigam AK, Bahadur D, J. Magn. Magn. Mater., 293, 55 (2005)

[18] Zhang DE, Zhang XJ, Ni XM, Zheng HG, Yang DD, J. Magn. Magn. Mater., 292, 79 (2005)

[19] Wang KM, Lee DS, Horng L, Chern G, J. Magn. Magn. Mater., 282, 73 (2004)

[20] Gao Z, Cui F, Zeng S, Guo L, Shi J, Microporous Mesoporous Mater., 132, 188 (2010)

[21] Konicki W, Sibera D, Mijowska E, Lendzion-Bielun Z, Narkiewicz U, J. Colloid Interface Sci., 398(15), 152 (2013)

[22] Zhang SX, Niu HY, Cai YQ, Zhao XL, Shi YL, Chem. Eng. J., 158(3), 599 (2010)

[23] Ai LH, Zhou Y, Jiang J, Desalination, 266(1-3), 72 (2011)

[24] Wu R, Qu J, Chen Y, Water Res., 39(4), 630 (2005)

[25] Virlan C, Ciocarlan RG, Roman T, Gherca D, Cornei N, Pui A, Acta Chem. Iasi, 21(1), 19 (2013)

[26] Bahgat M, Farghali AA, El Rouby W, Khedr M, Mohassab-Ahmed MY, Appl. Nanosci., 3(3), 251 (2013)

[27] Hashemian S, Salimi M, Chem. Eng. J., 188, 57 (2012)

[28] Feng J, Su L, Ma YH, Ren CL, Guo Q, Chen XG, Chem. Eng. J., 221, 16 (2013)

[29] Gunjakar JL, More AM, Shinde VR, Lokhande CD, J. Alloy. Compd., 465, 468 (2008)

[30] Wang L, Li J, Wang Y, Zhao L, Jiang Q, Chem. Eng. J., 181-182, 72 (2012)

[31] Gong RM, Zhu SX, Zhang DM, Chen J, Ni SJ, Guan R, Desalination, 230(1-3), 220 (2008)

[32] Hashemian S, Foroghimoqhadam A, Chem. Eng. J., 235, 299 (2014)

[33] Hashemian S, Mirshamsi M, J. Ind. Eng. Chem., 18(6), 2010 (2012)

[34] Lagergren S, Handlingar, 24, 1 (1898)

[35] Ho YS, McKay G, Wase DAJ, Foster CF, Adsorpt. Sci. Technol., 18, 639 (2000)

[36] Kumar R, Ansari MO, Barakat MA, Ind. Eng. Chem. Res., 53(17), 7167 (2014)

[37] Tavlieva MP, Genieva SD, Georgieva VG, Vlaev LT, J. Colloid Interface Sci., 409, 112 (2013)

[38] Ozkahraman B, Bal A, Acar I, Guclu G, Clean Soil Air Water, 39(11), 1001 (2011)

[39] Mane VS, Mall ID, Chandra S, J. Environ. Manage., 84(4), 390 (2007)

[40] Esan OS, Abiola ON, Owoyomi O, Aboluwoye CO, Osundiya MO, ISRN Phys. Chem. (2014), http://dx.doi.org/10.1155/2014/743532 (Article ID 743532, 12 pages).

[41] Karuppasamy A, Muthirulan P, Meenakshi Sundaram M, J. Chem. Pharm. Res., 4(12), 5101 (2012)

[42] Rehman MSU, Munir M, Ashfaq M, Rashid N, Nazar MF, Danish M, Han JI, Chem. Eng. J., 228, 54 (2013)

[43] Bhattacharyya KG, Sarma A, Dyes Pigment., 57(3), 211 (2003)

[44] Nandi BK, Goswami A, Purkait MK, J. Hazard. Mater., 161(1), 387 (2009)

[45] Kumar GV, Agrawal P, Hiremath L, Int. J. ChemTech Res., 4(1), 319 (2012)

[46] Wang Z, Zhang LS, Jing ZQ, Adv. Des. Manuf. II, 419-420, 525 (2009)