Utilization of sulfidated poly (acrylamide-vinyl acetate) as a new corrosion inhibitor for carbon steel in acidic media

M.R. Noor El-Din; E.A. Khamis

Journal of Industrial and Engineering Chemistry, Vol.24, 342-350, April, 2015

DOI10.1016/j.jiec.2014.10.007 Export Citation

Utilization of sulfidated poly (acrylamide-vinyl acetate) as a new corrosion inhibitor for carbon steel in acidic media

M.R. Noor El-Din, and E.A. Khamis^†

Egyptian Petroleum Research Institute (EPRI), 1 Ahmed El-Zomor St., Nasr City, 11727, Cairo, Egypt

E-mail:

This paper study the utilization of sulfidated poly (acrylamide-vinyl acetate) (SG), which is previously prepared by the expose of poly (acrylamide-vinyl acetate) copolymer (AG) to H2S gas (15 ppm), as a new corrosion inhibitor for carbon steel in acidic media. The corrosion inhibition efficiency of these inhibitors is detected in carbon steel surface in 1 M HCl solution by the weight loss and electrochemical techniques. Untreated and treated steel surfaces were examined by scanning electron microscopy (SEM). The obtained results show that the maximum inhibition efficiency (ηp) by SG inhibitor in 1 M HCl solution at 500 ppm and 303 K was 96.71%. Also, the potentiodynamic polarization curves indicated that the investigated inhibitors behave as a mixed type inhibitor. Adsorption of these inhibitors on the carbon steel surface was found to obey Langmuir's adsorption isotherm. Both of the computed quantum chemical properties viz., electron affinity (EA), highest occupied molecular orbital (EHOMO), the lowest unoccupied molecular orbital (ELUMO), energy gap ΔE = EHOMO-ELUMO, dipole moment (μ), log P and ΔN showed good correlation with experimental inhibition efficiency.

Keywords:H2S gas;Corrosion inhibitors;Mild steel;Polarization;Quantum chemical investigation

[References]

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Stirling D, The Royal Society of Chemistry, London, 2000.
Lu JG, Zheng YF, He DL, Sep. Purif. Technol., 52(2), 209 (2006)
Baird T, Denny PJ, Hoyle R, McMonagle F, Stirling D, Tweedy J, J. Chem. Soc.-Faraday Trans., 88, 3375 (1992)
Stirling D, The Sulfur Problem Cleaning Up Industrial Feedstocks, first ed., The Royal Society of Chemistry, Cambridge, UK, 2000.
Yuce AO, Mert BD, Kardas G, Dogru B, Yazıcı B, Corrosion Sci., 83, 310 (2014)
Mohan P, Kalaignan GP, J. Mater. Sci. Technol., 29, 1096 (2013)
Nam ND, Bui QV, Mathesh M, Tan MYJ, Forsyth M, Corrosion Sci., 76, 257 (2013)
Solmaz R, Sahin EA, Doner A, Kardas G, Corrosion Sci., 53, 3231 (2011)
Mert BD, Mert ME, Kardas G, Yazıcı B, Corrosion Sci., 53, 4265 (2011)
El-Haddad MN, Fouda AS, J. Dispersion Sci. Technol., 34, 1471 (2013)
El-Din MRN, Al-Sabagh AM, Hegazy MA, J. Dispersion Sci. Technol., 33, 1 (2012)
El-Din MRN, Khamis EA, J. Surfactant Deterg, 17, 795 (2014)
Arslan T, Kandemirli F, Ebenso EE, Love I, Alemu H, Corrosion Sci., 51, 35 (2009)
Li C, Liu MY, Pschirer NG, Baumgarten M, Mullen K, Chem. Rev., 110(11), 6817 (2010)
EL-Azeim Hussein AA, (M.Sc. thesis), Faculty of Science, Ain Shams University, Cairo, Egypt, 2014.
Behpour M, Ghoreishi SM, Khayatkashani M, Soltani N, Mater. Chem. Phys., 131(3), 621 (2012)
Palomar-Pardave M, Romero-Romo M, Herrera-Hernandez H, Abreu-Quijano MA, Natalya V, Likhanova J, Uruchurtu JM, Juarez-Garcıa, Corrosion Sci., 54, 231 (2012)
Deng S, Li X, Corrosion Sci., 55, 407 (2012)
Cao C, Corrosion Sci., 38, 2073 (1996)
Hassan HH, Abdelghani E, Amin MA, Electrochim. Acta, 52(22), 6359 (2007)
Abdel-Gabar AM, Abd-El-Nabey BA, Sidahmed IM, El-Zayady AM, Saadawy M, Corrosion Sci., 48, 2765 (2006)
Macdonald JR, Johanson WB, in: Macdonald JR (Ed.), John Wiley & Sons, New York, 1987.
Yadav DK, Quraishi MA, Maiti B, Corrosion Sci., 55, 254 (2012)
Migahed MA, Abdul-Raheim AM, Atta AM, Brostow W, Mater. Chem. Phys., 121(1-2), 208 (2010)
Hegazy MA, Corrosion Sci., 51, 2610 (2009)
Hegazy MA, Zaky MF, Corrosion Sci., 52, 1333 (2010)
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Hegazy MA, Abdallah M, Ahmed H, Corrosion Sci., 52, 2897 (2010)
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Quartarone G, Battilana M, Bonaldo L, Tortato T, Corrosion Sci., 50, 3467 (2008)
Bahrami MJ, Hosseini SMA, Pilvar P, Corrosion Sci., 52(2793) (2010)
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Politzer P, Truhlar DG, Plenum, New York, 1981.

[Referenced By]

[1] Montes D, Tocuyo E, Gonzalez E, Rodrıguez D, Solano R, Atencio R, Ramos MA, Moronta A, Microporous Mesoporous Mater., 168, 111 (2013)

[2] Stirling D, The Royal Society of Chemistry, London, 2000.

[3] Lu JG, Zheng YF, He DL, Sep. Purif. Technol., 52(2), 209 (2006)

[4] Baird T, Denny PJ, Hoyle R, McMonagle F, Stirling D, Tweedy J, J. Chem. Soc.-Faraday Trans., 88, 3375 (1992)

[5] Stirling D, The Sulfur Problem Cleaning Up Industrial Feedstocks, first ed., The Royal Society of Chemistry, Cambridge, UK, 2000.

[6] Yuce AO, Mert BD, Kardas G, Dogru B, Yazıcı B, Corrosion Sci., 83, 310 (2014)

[7] Mohan P, Kalaignan GP, J. Mater. Sci. Technol., 29, 1096 (2013)

[8] Nam ND, Bui QV, Mathesh M, Tan MYJ, Forsyth M, Corrosion Sci., 76, 257 (2013)

[9] Solmaz R, Sahin EA, Doner A, Kardas G, Corrosion Sci., 53, 3231 (2011)

[10] Mert BD, Mert ME, Kardas G, Yazıcı B, Corrosion Sci., 53, 4265 (2011)

[11] El-Haddad MN, Fouda AS, J. Dispersion Sci. Technol., 34, 1471 (2013)

[12] El-Din MRN, Al-Sabagh AM, Hegazy MA, J. Dispersion Sci. Technol., 33, 1 (2012)

[13] El-Din MRN, Khamis EA, J. Surfactant Deterg, 17, 795 (2014)

[14] Arslan T, Kandemirli F, Ebenso EE, Love I, Alemu H, Corrosion Sci., 51, 35 (2009)

[15] Li C, Liu MY, Pschirer NG, Baumgarten M, Mullen K, Chem. Rev., 110(11), 6817 (2010)

[16] EL-Azeim Hussein AA, (M.Sc. thesis), Faculty of Science, Ain Shams University, Cairo, Egypt, 2014.

[17] Behpour M, Ghoreishi SM, Khayatkashani M, Soltani N, Mater. Chem. Phys., 131(3), 621 (2012)

[18] Palomar-Pardave M, Romero-Romo M, Herrera-Hernandez H, Abreu-Quijano MA, Natalya V, Likhanova J, Uruchurtu JM, Juarez-Garcıa, Corrosion Sci., 54, 231 (2012)

[19] Deng S, Li X, Corrosion Sci., 55, 407 (2012)

[20] Cao C, Corrosion Sci., 38, 2073 (1996)

[21] Hassan HH, Abdelghani E, Amin MA, Electrochim. Acta, 52(22), 6359 (2007)

[22] Abdel-Gabar AM, Abd-El-Nabey BA, Sidahmed IM, El-Zayady AM, Saadawy M, Corrosion Sci., 48, 2765 (2006)

[23] Macdonald JR, Johanson WB, in: Macdonald JR (Ed.), John Wiley & Sons, New York, 1987.

[24] Yadav DK, Quraishi MA, Maiti B, Corrosion Sci., 55, 254 (2012)

[25] Migahed MA, Abdul-Raheim AM, Atta AM, Brostow W, Mater. Chem. Phys., 121(1-2), 208 (2010)

[26] Hegazy MA, Corrosion Sci., 51, 2610 (2009)

[27] Hegazy MA, Zaky MF, Corrosion Sci., 52, 1333 (2010)

[28] Oguzie EE, Li Y, Wang FH, Electrochim. Acta, 53(2), 909 (2007)

[29] Hegazy MA, Abdallah M, Ahmed H, Corrosion Sci., 52, 2897 (2010)

[30] Ei-Etre AY, J. Colloid Interface Sci., 314(2), 578 (2007)

[31] Quartarone G, Battilana M, Bonaldo L, Tortato T, Corrosion Sci., 50, 3467 (2008)

[32] Bahrami MJ, Hosseini SMA, Pilvar P, Corrosion Sci., 52(2793) (2010)

[33] Fang J, Li J, J. Mol. Struct. THEOCHEM, 593, 179 (2002)

[34] Bereket G, Hur E, Ogretir C, J. Mol. Struct. THEOCHEM, 578, 79 (2002)

[35] Musa AY, Kadhum AAH, Mohamad AB, Takriff MS, Daud AR, Kamarudin SK, Corrosion Sci., 52, 526 (2010)

[36] Khaled KF, Appl. Surf. Sci., 255(5), 1811 (2008)

[37] Ju H, Kai Z, Li Y, Corrosion Sci., 50, 865 (2008)

[38] Lukovits I, Kalman E, Zucchi F, Corrosion NACE, 57, 3 (2001)

[39] Hansch C, Leo A, Wiley, New York, NY, USA, 1979.

[40] Scrocco E, Tomasi J, Adv. Quant. Chem., 11, 115 (1979)

[41] Luque FJ, Lopez JM, Orozco M, Theor. Chem. Acc., 103, 343 (2000)

[42] Okulik N, Jubert AH, J. Mol. Des., 4, 17 (2005)

[43] Politzer P, Laurence PR, Jayasuriya K, Environ. Health Perspect., 61, 191 (1985)

[44] Scrocco E, Tomasi J, Topics in Current Chemistry, Springer, Berlin, 1973.

[45] Politzer P, Truhlar DG, Plenum, New York, 1981.