화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.25, 22-28, May, 2015
DOI10.1016/j.jiec.2014.10.008  Export Citation
Separation of Cd(II) from industrial wastewater via HFSLM: Equilibrium, kinetic and thermodynamic investigation
Dolapop Sribudda, Niti Sunsandee1, Prakorn Ramakul2, Ura Pancharoen†, and Suphot Phatanasri†
  • Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand
  • 1Government Pharmaceutical Organization, Ratchathewi, Bangkok 10400, Thailand
  • 2Department of Chemical Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Amphoe Muang 73000, Nakhon Pathom, Thailand
E-mail:,
Separation of Cd(II) from industrial wastewater via hollow fiber supported liquid membrane (HFSLM) was examined. The effect of pH of feed and stripping solutions, type and concentration of extractants were investigated. Optimal conditions were 0.12 M D2EHPA. pH of feed and stripping solutions were 5.5 and 3.0, respectively. Percentages of extraction and stripping of Cd(II) reached about 97.08% and 57.18%. Interestingly, an isotherm model was applied to the HFSLM process. It was noted that Langmuir model fitted in better than Freundlich model with a deviation of 7.76%. Thus, when Cd(II) ion was extracted inside HFSLM, a mono-layer consumption occurred.
Keywords:Cadmium;HFSLM;Equilibrium;Kinetic;Thermodynamic
  1. Benquella B, Benaissa H, Water Res., 36, 2463 (2002)
  2. Mohan D, Kunwar S, Water Res., 36, 2304 (2002)
  3. Nogawa K, Kobayashi E, Okubo Y, Suwazono Y, Biometals, 17, 581 (2004)
  4. Thailand regulatory discharge standards, Ministry of Industry, Thailand. 1996.
  5. Reddy BR, Priya DN, Kumar JR, Hydrometallurgy, 74, 277 (2004)
  6. Kumar V, Kumar M, Jha MK, Jeong J, Lee JC, Hydrometallurgy, 96, 230 (2009)
  7. Reddy BR, Priya DN, Rao SV, Radhika P, Hydrometallurgy, 77, 253 (2005)
  8. Davakhah R, Khanramaki F, Asgari M, Salimi B, Ashtari P, Shamsipur M, J. Radioanal. Nucl. Chem., 298, 125 (2013)
  9. Ansari SA, Mohapatra PK, Raut DR, Kumar M, Rajeswari B, Manchanda VK, J. Membr. Sci., 337(1-2), 304 (2009)
  10. Amaral JCBS, Morais CA, Miner. Eng., 23(6), 498 (2010)
  11. Ramakul P, Supajaroon T, Prapasawat T, Pancharoen U, Lothongkum AW, J. Ind. Eng. Chem., 15(2), 224 (2009)
  12. Parhi PK, Das NN, Sarangi K, J. Hazard. Mater., 172(2-3), 773 (2009)
  13. Swain B, Sarangi K, Das RP, J. Membr. Sci., 277(1-2), 240 (2006)
  14. Mortaheb HR, Kosuge H, Mokhtarani B, Amini MH, Banihashemi HR, J. Hazard. Mater., 165(1-3), 630 (2009)
  15. Prakorn R, Kwanta N, Ura P, Korean J. Chem. Eng., 21(6), 1212 (2004)
  16. Shiau CY, Chen PZ, Sep. Sci. Technol., 28, 2149 (1993)
  17. Vernekar PV, Patwardhan AW, Patwardhan AV, Ansari SA, Mohapatra PK, Manchanda VK, Sep. Sci. Technol., 48(7), 1003 (2013)
  18. Kandwal P, Ansari SA, Mohapatra PK, Manchanda VK, Sep. Sci. Technol., 46(6), 904 (2011)
  19. Ren ZQ, Meng HL, Zhang WD, Liu JT, Cui CH, Sep. Sci. Technol., 44(5), 1181 (2009)
  20. Peng JP, Rui L, Lio JF, Bin H, Hu XL, Jiang GB, Spectroc. Acta Pt. B-Atom. Spectr., 62, 499 (2007)
  21. Schulz G, Desalination, 68, 191 (1988)
  22. Kislik VS, Liquid Membranes: Principles and Applications in Chemical Separations and Wastewater Treatment, first ed., Elsevier B.V., Oxford, UK, 2000.
  23. Wannachod P, Chaturabul S, Pancharoen U, Lothongkum AW, Patthaveekongka W, J. Alloy. Compd., 509, 354 (2011)
  24. Lawrance GA, Introduction to Coordination Chemistry, first ed., John Wiley and Sons, West Sussex, UK, 2010.
  25. Pancharoen U, Somboonpanya S, Chaturabul S, Lothongkum AW, J. Alloy. Compd., 489, 72 (2010)
  26. Mortaheb HR, Zolfaghari A, Mokhtarani B, Amini MH, Mandanipour V, J. Hazard. Mater., 177(1-3), 660 (2010)
  27. Seader JD, Henley EJ, Roper DK, Separation Process Principles Chemical and Biochemical operation, third ed., John Wiley & Sons, New York, NY, 2005.
  28. Ghaedi M, Hosaininia R, Ghaedi AM, Vafaei A, Taghizadeh F, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 131, 601 (2014)
  29. Javadian H, J. Ind. Eng. Chem., 20, 4231 (2014)
  30. Song XL, Zhang Y, Yan CY, Jiang WJ, Chang CM, J. Colloid Interface Sci., 389, 213 (2013)
  31. Uddin MT, Islam MS, Abedin MZ, ARPN J. Eng. Appl. Sci., 2, 11 (2007)
  32. Okeola FO, Odebunmi EO, Adv. Environ. Biol., 4, 329 (2010)
  33. Gil A, Assis FCC, Albeniz S, Korili SA, Chem. Eng. J., 168(3), 1032 (2011)
  34. Mostaedi MT, Asadollahzadeh M, Hemmati A, Khosravi A, J. Taiwan Inst. Chem. Eng., 44, 295 (2013)