Development of poly-o-toluidine zirconium (IV) ethylenediamine as a new adsorbent for nitrate: Equilibrium modelling and thermodynamic studies

Nafisur Rahman; Mohammad Fazeel Khan

Journal of Industrial and Engineering Chemistry, Vol.25, 272-279, May, 2015

DOI10.1016/j.jiec.2014.11.004 Export Citation

Development of poly-o-toluidine zirconium (IV) ethylenediamine as a new adsorbent for nitrate: Equilibrium modelling and thermodynamic studies

Nafisur Rahman^†, and Mohammad Fazeel Khan

Department of Chemistry, Aligarh Muslim University Aligarh, 202002, Uttar Pradesh, India

E-mail:

Poly-o-toluidine zirconium(IV) ethylenediamine (PTZE) was synthesized to explore its behaviour towards nitrate sorption. The material was characterized by FTIR, XRD, TGA, DTA, SEM and TEM. The adsorption of nitrate onto PTZE was investigated in a batch system at 27 °C. The adsorption equilibrium data were fitted well to Freundlich isotherm model. A single-stage batch adsorption system was also designed from equilibrium data using Freundlich isotherm model. The thermodynamic parameters such as ΔG0, ΔH0 and ΔS0 for nitrate adsorption were calculated. The results showed that the adsorption process was spontaneous and endothermic in nature.

Keywords:Poly-o-toluidine zirconium(IV) ethylenediamine;Nitrate;Adsorption;Isotherm models;Error function

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Halsey G, J. Chem. Phys., 16, 931 (1948)
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[Referenced By]

[1] Liu A, Ming J, Ankumah RO, Sci. Total Environ., 346, 112 (2005)

[2] Camargo JA, Alonso A, Environ. Int., 32, 831 (2006)

[3] Jacinthe P, Dick WA, Brown LC, Soil Biol. Biochem., 32, 371 (2000)

[4] Neal C, Neal M, Wickhan H, Harrow M, Sci. Total Environ., 251-252, 459 (2000)

[5] George M, Wiklund L, Aastrup M, Pousette J, Thunholm BT, Saldeen B, Wernroth L, Zaren B, Holmberg L, Eur. J. Clin. Invest., 31, 1083 (2001)

[6] Nebbache S, Feeny V, Poudevigne IP, Alard D, J. Environ. Manage., 62, 389 (2001)

[7] Chiu H, Tsai S, Yang C, J. Toxicol. Environ. Health Part A, 70, 1000 (2007)

[8] Fewtrell L, Environ. Health Perspect., 112, 1371 (2004)

[9] World Health Organization, Nitrate and Nitrite in Drinking Water, Guidelines for Drinking Water Quality, WHO Press, Geneva, 2011.

[10] United States Environmental Protection Agency, 2011. Drinking water standards and health advisories. EPA 820-R-11-002. Washington DC.

[11] Mohseni-Bandpi A, Elliott DJ, Zazouli MA, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 11(35), 1 (2013)

[12] Filippis PD, Palma LD, Scarsella M, Verdone N, Chem. Eng. Trans., 32, 319 (2013)

[13] Shoeman JJ, Water SA, 35, 721 (2009)

[14] Koyuncu I, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 37, 1347 (2002)

[15] Kim J, Benjamin MM, Water Res., 38, 2053 (2004)

[16] Mishra PC, Islam M, Patel RK, Desalin. Water Treat., http://dx.doi.org/10.1080/19443994.2013.808586., 52, 5673 (2014)

[17] Maia MP, Rodrigues MA, Passos FB, Catal. Today, 123(1-4), 171 (2007)

[18] Onyango MS, Masukume M, Ochieng A, Otieno F, Water SA, 36, 655 (2010)

[19] Saad R, Hamoudi S, Belkacemi K, J. Porous Mat., 15, 315 (2008)

[20] Kim Y, Choi J, Water Res., 46, 6033 (2012)

[21] Zhan YH, Lin JW, Zhu ZL, J. Hazard. Mater., 186(2-3), 1972 (2011)

[22] Mandal S, Sahu MK, Patel RK, Water Res. India, 4, 51 (2013)

[23] Chabani M, Amrane A, Bensmaili A, J. Hazard. Mater., 165(1-3), 27 (2009)

[24] Dron J, Dodi A, J. Hazard. Mater., 190(1-3), 300 (2011)

[25] Hannachi C, Guesmi F, Missaoui K, Hamrouni B, Int. J. Technol., 1, 60 (2014)

[26] Chiban M, Soudani A, Sinan F, Persin M, Colloids Surf. B: Biointerfaces, 8, 267 (2011)

[27] Chiban M, Soudani A, Sinan F, Persin M, CLEAN-Soil Air Water, 39, 823 (2001)

[28] Chiban M, Soudani A, Sinan F, Persin M, J. Environ. Manage., 95, S61 (2012)

[29] Snell FD, Snell CT, third ed., Colorimetric Methods of Analysis, Vol. II, D. Van Nostrand Company, Inc, Princeton, USA, 1949p. 446.

[30] Snell FD, Snell CT, Colorimetric methods of analysis, Vol. I, VA, D. Van Nostrand Company, Inc, Princeton, USA, 1967p. 99.

[31] Qureshi SZ, Ahmad I, Khayer MR, Ann. Chim. Sci. Mater., 24, 531 (1999)

[32] Alberti G, Torracca E, J. Inorg. Nucl. Chem., 30, 3075 (1968)

[33] Namasivayam C, Sangeetha D, Indian J. Chem. Technol., 12(5), 513 (2005)

[34] Bhatnagar A, Ji M, Choi Y, Jung W, Lee S, Kim S, Lee G, Suk H, Kim H, Min B, Jeon B, Kang J, Sep. Purif. Technol., 43, 886 (2008)

[35] Bekele W, Faye G, Fernandez N, Int. J. Res. Pharm. Chem., 4, 192 (2014)

[36] Mishra PC, Patel RK, J. Environ. Manage., 90, 519 (2009)

[37] Mizuta K, Matsumoto T, Hatate Y, Nishihara K, Nakanishi T, Bioresour. Technol., 95(3), 255 (2004)

[38] Srivastava AL, Singh PK, Weng CH, Sharma YC, J. Hazard. Toxic Radioact. Waste. (2014), http://dx.doi.org/10.1061/(ASCE)HZ. 2153-5515.0000235,04014028(8).

[39] Pavlovic JB, Milenkovic JK, Rajic NZ, J. Serb. Chem. Soc., http://dx.doi.org/10.2298/JSCS140116038P., 79, 1309 (2014)

[40] Aroke UO, El-Nafty UA, Osha OA, Int. J. Emerg. Technol. Adv. Eng., 4, 475 (2014)

[41] Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)

[42] Mckay G, Use of Adsorbents for the Removal of Pollutants from Wastewaters, CRC Press, Boca Raton, FL, 1995.

[43] Temkin MJ, Pyzher V, Actaphysicochim. USSR, 12, 217 (1940)

[44] Kausar A, Bhatti HN, MacKinnon G, Colloids Surf. B: Biointerfaces, 111, 124 (2013)

[45] Halsey G, J. Chem. Phys., 16, 931 (1948)

[46] Horsfall M, Vicente JL, Bull. Chem. Soc. Ethiop., 21, 349 (2007)

[47] Dawood S, Sen TK, Water Res., 46, 1933 (2012)

[48] Rahman N, Haseen U, Ind. Eng. Chem. Res., 53(19), 8198 (2014)